Preparation and some properties of perfluoroalkoxy-substituted phthalocyanine complexes of iron(III), nickel(II) and zinc(II)

Tamotsu Sugimori; Shin Ichi Horike; Makoto Handa; Kuninobu Kasuga

doi:10.1016/S0020-1693(98)00104-2

Preparation and some properties of perfluoroalkoxy-substituted phthalocyanine complexes of iron(III), nickel(II) and zinc(II)

Tamotsu Sugimori^*, Shin Ichi Horike, Makoto Handa, Kuninobu Kasuga

^*Corresponding author for this work

Faculty of Liberal Arts and Sciences

Research output: Contribution to journal › Article › peer-review

45 Scopus citations

Abstract

Tetrakis(2′,2′,3′,3′,4′,4′,5′, 5′-octafluoropentoxy)phthalocyanine complexes of iron(III), nickel(II) and zinc(II) were prepared and characterized. The complexes were soluble in polar solvents such as ethanol and methanol but insoluble in less polar solvents such as benzene and toluene. The electron-withdrawing fluorine atoms in the substituents strongly affected the electrochemical and spectroscopic properties of the complexes.

Original language	English
Pages (from-to)	253-255
Number of pages	3
Journal	Inorganica Chimica Acta
Volume	278
Issue number	2
DOIs	https://doi.org/10.1016/S0020-1693(98)00104-2
State	Published - 1998/09/01

Keywords

Electrochemistry
Iron complexes
Nickel complexes
Perfluoroalkoxy-substituted complexes
Phthalocyanine complexes
Zinc complexes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S0020-1693(98)00104-2

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title = "Preparation and some properties of perfluoroalkoxy-substituted phthalocyanine complexes of iron(III), nickel(II) and zinc(II)",

abstract = "Tetrakis(2′,2′,3′,3′,4′,4′,5′, 5′-octafluoropentoxy)phthalocyanine complexes of iron(III), nickel(II) and zinc(II) were prepared and characterized. The complexes were soluble in polar solvents such as ethanol and methanol but insoluble in less polar solvents such as benzene and toluene. The electron-withdrawing fluorine atoms in the substituents strongly affected the electrochemical and spectroscopic properties of the complexes.",

keywords = "Electrochemistry, Iron complexes, Nickel complexes, Perfluoroalkoxy-substituted complexes, Phthalocyanine complexes, Zinc complexes",

author = "Tamotsu Sugimori and Horike, {Shin Ichi} and Makoto Handa and Kuninobu Kasuga",

note = "Funding Information: This work was supported ky II Grunt-in-Aid for Scientilic Resctrrch No. 09640668 from the Ministry oi{\textquoteright}E&tc~ttion, Science, Sports ml Culture.",

year = "1998",

month = sep,

day = "1",

doi = "10.1016/S0020-1693(98)00104-2",

language = "英語",

volume = "278",

pages = "253--255",

journal = "Inorganica Chimica Acta",

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publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Preparation and some properties of perfluoroalkoxy-substituted phthalocyanine complexes of iron(III), nickel(II) and zinc(II)

AU - Sugimori, Tamotsu

AU - Horike, Shin Ichi

AU - Handa, Makoto

AU - Kasuga, Kuninobu

N1 - Funding Information: This work was supported ky II Grunt-in-Aid for Scientilic Resctrrch No. 09640668 from the Ministry oi’E&tc~ttion, Science, Sports ml Culture.

PY - 1998/9/1

Y1 - 1998/9/1

N2 - Tetrakis(2′,2′,3′,3′,4′,4′,5′, 5′-octafluoropentoxy)phthalocyanine complexes of iron(III), nickel(II) and zinc(II) were prepared and characterized. The complexes were soluble in polar solvents such as ethanol and methanol but insoluble in less polar solvents such as benzene and toluene. The electron-withdrawing fluorine atoms in the substituents strongly affected the electrochemical and spectroscopic properties of the complexes.

AB - Tetrakis(2′,2′,3′,3′,4′,4′,5′, 5′-octafluoropentoxy)phthalocyanine complexes of iron(III), nickel(II) and zinc(II) were prepared and characterized. The complexes were soluble in polar solvents such as ethanol and methanol but insoluble in less polar solvents such as benzene and toluene. The electron-withdrawing fluorine atoms in the substituents strongly affected the electrochemical and spectroscopic properties of the complexes.

KW - Electrochemistry

KW - Iron complexes

KW - Nickel complexes

KW - Perfluoroalkoxy-substituted complexes

KW - Phthalocyanine complexes

KW - Zinc complexes

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U2 - 10.1016/S0020-1693(98)00104-2

DO - 10.1016/S0020-1693(98)00104-2

M3 - 学術論文

AN - SCOPUS:0012140121

SN - 0020-1693

VL - 278

SP - 253

EP - 255

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 2

ER -

Preparation and some properties of perfluoroalkoxy-substituted phthalocyanine complexes of iron(III), nickel(II) and zinc(II)

Abstract

Keywords

ASJC Scopus subject areas

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