Polymer complexes of rhodium acetamidate dimers bridged by pyrazine, 4,4′-bipyridine, and 1,4-diazabicyclo[2.2.2]octane

Makoto Handa; Yasuhiro Muraki; Seiichiro Kawabata; Tamotsu Sugimori; Ichiro Hiromitsu; Masahiro Mikuriya; Kuninobu Kasuga

doi:10.1080/713738649

Polymer complexes of rhodium acetamidate dimers bridged by pyrazine, 4,4′-bipyridine, and 1,4-diazabicyclo[2.2.2]octane

Makoto Handa^*, Yasuhiro Muraki, Seiichiro Kawabata, Tamotsu Sugimori, Ichiro Hiromitsu, Masahiro Mikuriya, Kuninobu Kasuga

^*Corresponding author for this work

Faculty of Liberal Arts and Sciences

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

Polymer complexes of rhodium (II,II and II,III) acetamidate dimers bridged by pyrazine (pyz), 4,4′-bipyridine (4,4′-bpy), and 1,4-diazabicyclo[2.2.2]octane (dabco) have been prepared and characterized. Doping of the Rh(II,II) polymers with NOBF₄ increased the electrical conductivities when the bridging ligands were pyz and 4,4′-bpy. The magnetic interaction through the bridging ligands was found to be weak for the Rh(II,III) polymers.

Original language	English
Pages (from-to)	327-332
Number of pages	6
Journal	Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
Volume	379
DOIs	https://doi.org/10.1080/713738649
State	Published - 2002

Keywords

1,4-diazabicyclo[2.2.2]octane
4,4′-bipyridine
Conductivity
Magnetism
Polymer complexes
Pyrazine
Rhodium acetamidate

ASJC Scopus subject areas

Condensed Matter Physics

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10.1080/713738649

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Handa, M., Muraki, Y., Kawabata, S., Sugimori, T., Hiromitsu, I., Mikuriya, M., & Kasuga, K. (2002). Polymer complexes of rhodium acetamidate dimers bridged by pyrazine, 4,4′-bipyridine, and 1,4-diazabicyclo[2.2.2]octane. Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, 379, 327-332. https://doi.org/10.1080/713738649

@article{524bca8c3c6a4d9fb95cd02e7904fdfb,

title = "Polymer complexes of rhodium acetamidate dimers bridged by pyrazine, 4,4′-bipyridine, and 1,4-diazabicyclo[2.2.2]octane",

abstract = "Polymer complexes of rhodium (II,II and II,III) acetamidate dimers bridged by pyrazine (pyz), 4,4′-bipyridine (4,4′-bpy), and 1,4-diazabicyclo[2.2.2]octane (dabco) have been prepared and characterized. Doping of the Rh(II,II) polymers with NOBF4 increased the electrical conductivities when the bridging ligands were pyz and 4,4′-bpy. The magnetic interaction through the bridging ligands was found to be weak for the Rh(II,III) polymers.",

keywords = "1,4-diazabicyclo[2.2.2]octane, 4,4′-bipyridine, Conductivity, Magnetism, Polymer complexes, Pyrazine, Rhodium acetamidate",

author = "Makoto Handa and Yasuhiro Muraki and Seiichiro Kawabata and Tamotsu Sugimori and Ichiro Hiromitsu and Masahiro Mikuriya and Kuninobu Kasuga",

year = "2002",

doi = "10.1080/713738649",

language = "英語",

volume = "379",

pages = "327--332",

journal = "Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals",

issn = "1058-725X",

publisher = "Taylor and Francis Ltd.",

}

Handa, M, Muraki, Y, Kawabata, S, Sugimori, T, Hiromitsu, I, Mikuriya, M & Kasuga, K 2002, 'Polymer complexes of rhodium acetamidate dimers bridged by pyrazine, 4,4′-bipyridine, and 1,4-diazabicyclo[2.2.2]octane', Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, vol. 379, pp. 327-332. https://doi.org/10.1080/713738649

Polymer complexes of rhodium acetamidate dimers bridged by pyrazine, 4,4′-bipyridine, and 1,4-diazabicyclo[2.2.2]octane. / Handa, Makoto; Muraki, Yasuhiro; Kawabata, Seiichiro et al.
In: Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, Vol. 379, 2002, p. 327-332.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Polymer complexes of rhodium acetamidate dimers bridged by pyrazine, 4,4′-bipyridine, and 1,4-diazabicyclo[2.2.2]octane

AU - Handa, Makoto

AU - Muraki, Yasuhiro

AU - Kawabata, Seiichiro

AU - Sugimori, Tamotsu

AU - Hiromitsu, Ichiro

AU - Mikuriya, Masahiro

AU - Kasuga, Kuninobu

PY - 2002

Y1 - 2002

N2 - Polymer complexes of rhodium (II,II and II,III) acetamidate dimers bridged by pyrazine (pyz), 4,4′-bipyridine (4,4′-bpy), and 1,4-diazabicyclo[2.2.2]octane (dabco) have been prepared and characterized. Doping of the Rh(II,II) polymers with NOBF4 increased the electrical conductivities when the bridging ligands were pyz and 4,4′-bpy. The magnetic interaction through the bridging ligands was found to be weak for the Rh(II,III) polymers.

AB - Polymer complexes of rhodium (II,II and II,III) acetamidate dimers bridged by pyrazine (pyz), 4,4′-bipyridine (4,4′-bpy), and 1,4-diazabicyclo[2.2.2]octane (dabco) have been prepared and characterized. Doping of the Rh(II,II) polymers with NOBF4 increased the electrical conductivities when the bridging ligands were pyz and 4,4′-bpy. The magnetic interaction through the bridging ligands was found to be weak for the Rh(II,III) polymers.

KW - 1,4-diazabicyclo[2.2.2]octane

KW - 4,4′-bipyridine

KW - Conductivity

KW - Magnetism

KW - Polymer complexes

KW - Pyrazine

KW - Rhodium acetamidate

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U2 - 10.1080/713738649

DO - 10.1080/713738649

M3 - 学術論文

AN - SCOPUS:3142770654

SN - 1058-725X

VL - 379

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EP - 332

JO - Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals

JF - Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals

ER -

Polymer complexes of rhodium acetamidate dimers bridged by pyrazine, 4,4′-bipyridine, and 1,4-diazabicyclo[2.2.2]octane

Abstract

Keywords

ASJC Scopus subject areas

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