Abstract
Photoelectron spectroscopy has been applied to investigate electron emissions from excited atomic fragments in the vicinity of the K-shell ionization threshold of N2. It is found that low kinetic energy electrons are emitted in the photon energy region both immediately below and above the K-shell ionization threshold. The electron emissions are attributable to autoionization from the excited fragments in low-n Rydberg states. The N2+* states leading to the formation of the excited fragments which autoionize with emitting slow electrons, are populated not only by spectator Auger decay from the core-excited states, but also by the recapture of slow photoelectrons into the Rydberg orbitals.
Original language | English |
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Pages (from-to) | 289-293 |
Number of pages | 5 |
Journal | Journal of Electron Spectroscopy and Related Phenomena |
Volume | 156-158 |
DOIs | |
State | Published - 2007/05 |
Keywords
- Excited atomic fragments
- Low energy electron emission
- Molecular inner-shell photoionization
- Photoelectron spectroscopy
ASJC Scopus subject areas
- Electronic, Optical and Magnetic Materials
- Radiation
- Atomic and Molecular Physics, and Optics
- Condensed Matter Physics
- Spectroscopy
- Physical and Theoretical Chemistry