Paddlewheel-type diruthenium(iii,iii) tetrakis(2-aminopyridinate) complexes with NIR absorption features: Combined experimental and theoretical study

Keyphrases

• CIS2 100%
• Density Functional Calculations 100%
• Tetrakis 100%
• Absorption Feature 100%
• Diruthenium 100%
• NIR Absorption 100%
• Aminopyridinates 100%
• Paddle Wheel 100%
• Temperature Effect 50%
• X-ray Diffraction (XRD) Analysis 50%
• Ligand-to-metal Charge Transfer 50%
• Absorption Bands 50%
• Cyclic Voltammetry 50%
• Spin State 50%
• Reduction Method 50%
• Redox Potential 50%
• Oxidation State 50%
• Magnetic Susceptibility Measurement 50%
• Triplet State 50%
• Near-infrared Absorption 50%
• Axial Position 50%
• 2-aminopyridine 50%
• Structural Isomers 50%
• One-electron Reduction 50%
• Transition Characteristics 50%
• 2-Amino-4-methylpyridine 50%
• Zero-point Energy 50%
• Chloride Ligand 50%
• Hamp 50%

Chemistry

• Density Functional Theory 100%
• Cyclic Voltammetry 50%
• Single Crystal X-Ray Diffraction 50%
• Density Functional Theory 50%
• X-Ray Diffraction 50%
• Spin State 50%
• Redox Potential 50%
• Magnetic Susceptibility Measurement 50%
• Triplet State 50%
• Aminopyridine 50%
• Constitutional Isomer 50%
• 4-Methylpyridine 50%
• Zero Point Energy 50%
• stability 50%
• Absorption Spectra 50%