Oxygenates synthesis from 1-hexene and syngas over supported cobalt catalysts

X. Q. Qiu; N. Tsubaki; K. Fujimoto; Q. M. Zhu

doi:10.1016/j.fuproc.2003.11.042

Oxygenates synthesis from 1-hexene and syngas over supported cobalt catalysts

X. Q. Qiu^*, N. Tsubaki, K. Fujimoto, Q. M. Zhu

^*Corresponding author for this work

Applied Chemistry

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

The supported cobalt catalyst, such as Co/SiO₂, was found to be very active and selective for the synthesis of oxygenates (alcohols and aldehydes) from syngas and 1-hexene under mild reaction conditions. The addition of methanol or ethanol to the reaction system could greatly improve the catalytic activity. Esters and ethers were produced in this reaction system. The methanol and ethanol could act not only as solvent but also as reactant to react with the produced heptanal, resulting the great increasing of 1-hexene conversion.

Original language	English
Pages (from-to)	1193-1200
Number of pages	8
Journal	Fuel Processing Technology
Volume	85
Issue number	8-10
DOIs	https://doi.org/10.1016/j.fuproc.2003.11.042
State	Published - 2004/07/15

Keywords

1-Hexene
Heterogeneous hydroformylation
Oxygenate fuel
Solvent effect
Supported cobalt catalyst

ASJC Scopus subject areas

General Chemical Engineering
Fuel Technology
Energy Engineering and Power Technology

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10.1016/j.fuproc.2003.11.042

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@article{1a7338672e5a405e96d420c98c7514cf,

title = "Oxygenates synthesis from 1-hexene and syngas over supported cobalt catalysts",

abstract = "The supported cobalt catalyst, such as Co/SiO2, was found to be very active and selective for the synthesis of oxygenates (alcohols and aldehydes) from syngas and 1-hexene under mild reaction conditions. The addition of methanol or ethanol to the reaction system could greatly improve the catalytic activity. Esters and ethers were produced in this reaction system. The methanol and ethanol could act not only as solvent but also as reactant to react with the produced heptanal, resulting the great increasing of 1-hexene conversion.",

keywords = "1-Hexene, Heterogeneous hydroformylation, Oxygenate fuel, Solvent effect, Supported cobalt catalyst",

author = "Qiu, {X. Q.} and N. Tsubaki and K. Fujimoto and Zhu, {Q. M.}",

note = "Funding Information: This work was sponsored by Genesis Research Institute, Toyota Motors.",

year = "2004",

month = jul,

day = "15",

doi = "10.1016/j.fuproc.2003.11.042",

language = "英語",

volume = "85",

pages = "1193--1200",

journal = "Fuel Processing Technology",

issn = "0378-3820",

publisher = "Elsevier B.V.",

number = "8-10",

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TY - JOUR

T1 - Oxygenates synthesis from 1-hexene and syngas over supported cobalt catalysts

AU - Qiu, X. Q.

AU - Tsubaki, N.

AU - Fujimoto, K.

AU - Zhu, Q. M.

N1 - Funding Information: This work was sponsored by Genesis Research Institute, Toyota Motors.

PY - 2004/7/15

Y1 - 2004/7/15

N2 - The supported cobalt catalyst, such as Co/SiO2, was found to be very active and selective for the synthesis of oxygenates (alcohols and aldehydes) from syngas and 1-hexene under mild reaction conditions. The addition of methanol or ethanol to the reaction system could greatly improve the catalytic activity. Esters and ethers were produced in this reaction system. The methanol and ethanol could act not only as solvent but also as reactant to react with the produced heptanal, resulting the great increasing of 1-hexene conversion.

AB - The supported cobalt catalyst, such as Co/SiO2, was found to be very active and selective for the synthesis of oxygenates (alcohols and aldehydes) from syngas and 1-hexene under mild reaction conditions. The addition of methanol or ethanol to the reaction system could greatly improve the catalytic activity. Esters and ethers were produced in this reaction system. The methanol and ethanol could act not only as solvent but also as reactant to react with the produced heptanal, resulting the great increasing of 1-hexene conversion.

KW - 1-Hexene

KW - Heterogeneous hydroformylation

KW - Oxygenate fuel

KW - Solvent effect

KW - Supported cobalt catalyst

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U2 - 10.1016/j.fuproc.2003.11.042

DO - 10.1016/j.fuproc.2003.11.042

M3 - 学術論文

AN - SCOPUS:2342535828

SN - 0378-3820

VL - 85

SP - 1193

EP - 1200

JO - Fuel Processing Technology

JF - Fuel Processing Technology

IS - 8-10

ER -

Oxygenates synthesis from 1-hexene and syngas over supported cobalt catalysts

Abstract

Keywords

ASJC Scopus subject areas

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