Oxide transfer reaction from carbonate to metal-CO complex, affording metal-η1-CO2 complex and carbon dioxide

Hiroshi Nakajima; Kiyoshi Tsuge; Koji Tanaka

doi:10.1246/cl.1997.485

Oxide transfer reaction from carbonate to metal-CO complex, affording metal-η¹-CO₂ complex and carbon dioxide

Hiroshi Nakajima, Kiyoshi Tsuge, Koji Tanaka^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

The unprecedented oxide transfer reaction from CO₃^2- to the carbonyl complex, [Ru(bpy)₂(CO)₂]²⁺ in aprotic media is described. The oxide transfer proceeds via the 1:1 adduct formation, to afford Ru(bpy)₂(CO)(η¹-CO₂) and CO₂.

Original language	English
Pages (from-to)	485-486
Number of pages	2
Journal	Chemistry Letters
Issue number	6
DOIs	https://doi.org/10.1246/cl.1997.485
State	Published - 1997

ASJC Scopus subject areas

General Chemistry

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10.1246/cl.1997.485

Cite this

@article{ac519ca87249411c842d0b0e837bdb73,

title = "Oxide transfer reaction from carbonate to metal-CO complex, affording metal-η1-CO2 complex and carbon dioxide",

abstract = "The unprecedented oxide transfer reaction from CO32- to the carbonyl complex, [Ru(bpy)2(CO)2]2+ in aprotic media is described. The oxide transfer proceeds via the 1:1 adduct formation, to afford Ru(bpy)2(CO)(η1-CO2) and CO2.",

author = "Hiroshi Nakajima and Kiyoshi Tsuge and Koji Tanaka",

year = "1997",

doi = "10.1246/cl.1997.485",

language = "英語",

pages = "485--486",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "Oxford University Press",

number = "6",

}

TY - JOUR

T1 - Oxide transfer reaction from carbonate to metal-CO complex, affording metal-η1-CO2 complex and carbon dioxide

AU - Nakajima, Hiroshi

AU - Tsuge, Kiyoshi

AU - Tanaka, Koji

PY - 1997

Y1 - 1997

N2 - The unprecedented oxide transfer reaction from CO32- to the carbonyl complex, [Ru(bpy)2(CO)2]2+ in aprotic media is described. The oxide transfer proceeds via the 1:1 adduct formation, to afford Ru(bpy)2(CO)(η1-CO2) and CO2.

AB - The unprecedented oxide transfer reaction from CO32- to the carbonyl complex, [Ru(bpy)2(CO)2]2+ in aprotic media is described. The oxide transfer proceeds via the 1:1 adduct formation, to afford Ru(bpy)2(CO)(η1-CO2) and CO2.

UR - http://www.scopus.com/inward/record.url?scp=0039995136&partnerID=8YFLogxK

U2 - 10.1246/cl.1997.485

DO - 10.1246/cl.1997.485

M3 - 学術論文

AN - SCOPUS:0039995136

SN - 0366-7022

SP - 485

EP - 486

JO - Chemistry Letters

JF - Chemistry Letters

IS - 6