Orientation and substituent effects on the properties of the diacetylene-group connected octaethylporphyrin-dihexylbithiophene derivatives (OEP-DHBTh-X) carrying electron-withdrawing groups

Naoto Hayashi; Takashi Nishihara; Takuya Matsukihira; Hiroki Nakashima; Keiko Miyabayashi; Mikio Miyake; Hiroyuki Higuchi

doi:10.1246/bcsj.80.371

Orientation and substituent effects on the properties of the diacetylene-group connected octaethylporphyrin-dihexylbithiophene derivatives (OEP-DHBTh-X) carrying electron-withdrawing groups

Naoto Hayashi, Takashi Nishihara, Takuya Matsukihira, Hiroki Nakashima, Keiko Miyabayashi, Mikio Miyake, Hiroyuki Higuchi^*

^*Corresponding author for this work

Department of Chemistry

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11 Scopus citations

Abstract

Orientational isomers of the octaethylporphyrin-dihexylbithiophene (OEP-DHBTh) derivatives connected with a diacetylene linkage were synthesized, with various electron-withdrawing substituents X attached at the ends. The effects of DHBTh orientation and X substituent on the properties of OEP-DHBTh-X (X = H, Br, CN, CHO, and NO₂) were studied and compared with those of related OEP derivatives.

Original language	English
Pages (from-to)	371-386
Number of pages	16
Journal	Bulletin of the Chemical Society of Japan
Volume	80
Issue number	2
DOIs	https://doi.org/10.1246/bcsj.80.371
State	Published - 2007

ASJC Scopus subject areas

General Chemistry

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Hayashi, N., Nishihara, T., Matsukihira, T., Nakashima, H., Miyabayashi, K., Miyake, M., & Higuchi, H. (2007). Orientation and substituent effects on the properties of the diacetylene-group connected octaethylporphyrin-dihexylbithiophene derivatives (OEP-DHBTh-X) carrying electron-withdrawing groups. Bulletin of the Chemical Society of Japan, 80(2), 371-386. https://doi.org/10.1246/bcsj.80.371

@article{d6afa1ec01fb4df5a299b7784e2ea289,

title = "Orientation and substituent effects on the properties of the diacetylene-group connected octaethylporphyrin-dihexylbithiophene derivatives (OEP-DHBTh-X) carrying electron-withdrawing groups",

abstract = "Orientational isomers of the octaethylporphyrin-dihexylbithiophene (OEP-DHBTh) derivatives connected with a diacetylene linkage were synthesized, with various electron-withdrawing substituents X attached at the ends. The effects of DHBTh orientation and X substituent on the properties of OEP-DHBTh-X (X = H, Br, CN, CHO, and NO2) were studied and compared with those of related OEP derivatives.",

author = "Naoto Hayashi and Takashi Nishihara and Takuya Matsukihira and Hiroki Nakashima and Keiko Miyabayashi and Mikio Miyake and Hiroyuki Higuchi",

year = "2007",

doi = "10.1246/bcsj.80.371",

language = "英語",

volume = "80",

pages = "371--386",

journal = "Bulletin of the Chemical Society of Japan",

issn = "0009-2673",

publisher = "Oxford University Press",

number = "2",

}

Hayashi, N, Nishihara, T, Matsukihira, T, Nakashima, H, Miyabayashi, K, Miyake, M & Higuchi, H 2007, 'Orientation and substituent effects on the properties of the diacetylene-group connected octaethylporphyrin-dihexylbithiophene derivatives (OEP-DHBTh-X) carrying electron-withdrawing groups', Bulletin of the Chemical Society of Japan, vol. 80, no. 2, pp. 371-386. https://doi.org/10.1246/bcsj.80.371

Orientation and substituent effects on the properties of the diacetylene-group connected octaethylporphyrin-dihexylbithiophene derivatives (OEP-DHBTh-X) carrying electron-withdrawing groups. / Hayashi, Naoto; Nishihara, Takashi; Matsukihira, Takuya et al.
In: Bulletin of the Chemical Society of Japan, Vol. 80, No. 2, 2007, p. 371-386.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Orientation and substituent effects on the properties of the diacetylene-group connected octaethylporphyrin-dihexylbithiophene derivatives (OEP-DHBTh-X) carrying electron-withdrawing groups

AU - Hayashi, Naoto

AU - Nishihara, Takashi

AU - Matsukihira, Takuya

AU - Nakashima, Hiroki

AU - Miyabayashi, Keiko

AU - Miyake, Mikio

AU - Higuchi, Hiroyuki

PY - 2007

Y1 - 2007

N2 - Orientational isomers of the octaethylporphyrin-dihexylbithiophene (OEP-DHBTh) derivatives connected with a diacetylene linkage were synthesized, with various electron-withdrawing substituents X attached at the ends. The effects of DHBTh orientation and X substituent on the properties of OEP-DHBTh-X (X = H, Br, CN, CHO, and NO2) were studied and compared with those of related OEP derivatives.

AB - Orientational isomers of the octaethylporphyrin-dihexylbithiophene (OEP-DHBTh) derivatives connected with a diacetylene linkage were synthesized, with various electron-withdrawing substituents X attached at the ends. The effects of DHBTh orientation and X substituent on the properties of OEP-DHBTh-X (X = H, Br, CN, CHO, and NO2) were studied and compared with those of related OEP derivatives.

UR - http://www.scopus.com/inward/record.url?scp=33847106458&partnerID=8YFLogxK

U2 - 10.1246/bcsj.80.371

DO - 10.1246/bcsj.80.371

M3 - 学術論文

AN - SCOPUS:33847106458

SN - 0009-2673

VL - 80

SP - 371

EP - 386

JO - Bulletin of the Chemical Society of Japan

JF - Bulletin of the Chemical Society of Japan

IS - 2

ER -

Orientation and substituent effects on the properties of the diacetylene-group connected octaethylporphyrin-dihexylbithiophene derivatives (OEP-DHBTh-X) carrying electron-withdrawing groups

Abstract

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