Octahedral arrangement of porphyrin moieties around hexarhenium(III) cluster cores: Structure of (μ3-Selenido)hexa-(5-(4-pyridyl)-10,15,20-tritolylporphyrin)- hexarhenium(III) (2+)

Ai Itasaka; Masaaki Abe; Takashi Yoshimura; Kiyoshi Tsuge; Masamitsu Suzuki; Taira Imamura; Yoichi Sasaki

doi:10.1002/1521-3773(20020201)41:3<463::AID-ANIE463>3.0.CO;2-7

Octahedral arrangement of porphyrin moieties around hexarhenium(III) cluster cores: Structure of (μ₃-Selenido)hexa-(5-(4-pyridyl)-10,15,20-tritolylporphyrin)- hexarhenium(III) (2+)

Ai Itasaka, Masaaki Abe, Takashi Yoshimura, Kiyoshi Tsuge, Masamitsu Suzuki, Taira Imamura, Yoichi Sasaki

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

39 Scopus citations

Abstract

A porphyrin ball: An octahedral arrangement of six porphyrins is achieved by the coordination of 5-(4-pyridyl)-10,15,20-tritolylporphyrins (H₂PyT₃P) to the octa(μ₃-S/μ₃-Se)hexarhenium(III) core. Six porphyrin ligands are arranged virtually in an S₆ manner as the X-ray structural analysis of [Re₆(μ₃-S)₈(H₂PyT ₃P)₆](SbF₆)₂ shows (see picture).

Original language	English
Pages (from-to)	463-466
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	41
Issue number	3
DOIs	https://doi.org/10.1002/1521-3773(20020201)41:3<463::AID-ANIE463>3.0.CO;2-7
State	Published - 2002/02/01

Keywords

Cluster compounds
Porphyrinoids
Rhenium
Supramolecular chemistry

ASJC Scopus subject areas

Catalysis
General Chemistry

Access to Document

10.1002/1521-3773(20020201)41:3<463::AID-ANIE463>3.0.CO;2-7

Cite this

Itasaka, A., Abe, M., Yoshimura, T., Tsuge, K., Suzuki, M., Imamura, T., & Sasaki, Y. (2002). Octahedral arrangement of porphyrin moieties around hexarhenium(III) cluster cores: Structure of (μ₃-Selenido)hexa-(5-(4-pyridyl)-10,15,20-tritolylporphyrin)- hexarhenium(III) (2+). Angewandte Chemie - International Edition, 41(3), 463-466. https://doi.org/10.1002/1521-3773(20020201)41:3<463::AID-ANIE463>3.0.CO;2-7

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title = "Octahedral arrangement of porphyrin moieties around hexarhenium(III) cluster cores: Structure of (μ3-Selenido)hexa-(5-(4-pyridyl)-10,15,20-tritolylporphyrin)- hexarhenium(III) (2+)",

abstract = "A porphyrin ball: An octahedral arrangement of six porphyrins is achieved by the coordination of 5-(4-pyridyl)-10,15,20-tritolylporphyrins (H2PyT3P) to the octa(μ3-S/μ3-Se)hexarhenium(III) core. Six porphyrin ligands are arranged virtually in an S6 manner as the X-ray structural analysis of [Re6(μ3-S)8(H2PyT 3P)6](SbF6)2 shows (see picture).",

keywords = "Cluster compounds, Porphyrinoids, Rhenium, Supramolecular chemistry",

author = "Ai Itasaka and Masaaki Abe and Takashi Yoshimura and Kiyoshi Tsuge and Masamitsu Suzuki and Taira Imamura and Yoichi Sasaki",

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Itasaka, A, Abe, M, Yoshimura, T, Tsuge, K, Suzuki, M, Imamura, T & Sasaki, Y 2002, 'Octahedral arrangement of porphyrin moieties around hexarhenium(III) cluster cores: Structure of (μ₃-Selenido)hexa-(5-(4-pyridyl)-10,15,20-tritolylporphyrin)- hexarhenium(III) (2+)', Angewandte Chemie - International Edition, vol. 41, no. 3, pp. 463-466. https://doi.org/10.1002/1521-3773(20020201)41:3<463::AID-ANIE463>3.0.CO;2-7

Octahedral arrangement of porphyrin moieties around hexarhenium(III) cluster cores: Structure of (μ₃-Selenido)hexa-(5-(4-pyridyl)-10,15,20-tritolylporphyrin)- hexarhenium(III) (2+). / Itasaka, Ai; Abe, Masaaki; Yoshimura, Takashi et al.
In: Angewandte Chemie - International Edition, Vol. 41, No. 3, 01.02.2002, p. 463-466.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Octahedral arrangement of porphyrin moieties around hexarhenium(III) cluster cores

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AU - Itasaka, Ai

AU - Abe, Masaaki

AU - Yoshimura, Takashi

AU - Tsuge, Kiyoshi

AU - Suzuki, Masamitsu

AU - Imamura, Taira

AU - Sasaki, Yoichi

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Itasaka A, Abe M, Yoshimura T, Tsuge K, Suzuki M, Imamura T et al. Octahedral arrangement of porphyrin moieties around hexarhenium(III) cluster cores: Structure of (μ₃-Selenido)hexa-(5-(4-pyridyl)-10,15,20-tritolylporphyrin)- hexarhenium(III) (2+). Angewandte Chemie - International Edition. 2002 Feb 1;41(3):463-466. doi: 10.1002/1521-3773(20020201)41:3<463::AID-ANIE463>3.0.CO;2-7