Observation and analysis of the Δv=5 stretch overtone band transition of15nh3

Yoshiki Moriwaki; Ken’Ichi Nakagawa; Tadao Shimizu

doi:10.1143/JJAP.30.2901

Observation and analysis of the Δv=5 stretch overtone band transition of¹⁵nh₃

Yoshiki Moriwaki, Ken’Ichi Nakagawa^*, Tadao Shimizu

^*Corresponding author for this work

Department of Physics

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The absorption spectra of the Δv = 5 stretch overtone band transition of¹⁵NH₃in the visible region (648 nm band) are observed by the photoacoustic method for the first time. The resolution is 0.01 cm^-1. The observed Stark spectra at electric field high enough to resolve M components are helpfully employed in assignment of the rotation and inversion transitions. The vibrational level structure is well explained in terms of the local mode theory. The rotational constants and isotope shift are obtained.

Original language	English
Pages (from-to)	2901-2907
Number of pages	7
Journal	Japanese Journal of Applied Physics
Volume	30
Issue number	11R
DOIs	https://doi.org/10.1143/JJAP.30.2901
State	Published - 1991/11

Keywords

Highly excited vibrational state
Local mode vibration
N15ammonia
Overtone band
Photoacoustic spectroscopy
Stark spectroscopy

ASJC Scopus subject areas

General Engineering
General Physics and Astronomy

Access to Document

10.1143/JJAP.30.2901

Cite this

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title = "Observation and analysis of the Δv=5 stretch overtone band transition of15nh3",

abstract = "The absorption spectra of the Δv = 5 stretch overtone band transition of15NH3in the visible region (648 nm band) are observed by the photoacoustic method for the first time. The resolution is 0.01 cm-1. The observed Stark spectra at electric field high enough to resolve M components are helpfully employed in assignment of the rotation and inversion transitions. The vibrational level structure is well explained in terms of the local mode theory. The rotational constants and isotope shift are obtained.",

keywords = "Highly excited vibrational state, Local mode vibration, N15ammonia, Overtone band, Photoacoustic spectroscopy, Stark spectroscopy",

author = "Yoshiki Moriwaki and Ken{\textquoteright}Ichi Nakagawa and Tadao Shimizu",

year = "1991",

month = nov,

doi = "10.1143/JJAP.30.2901",

language = "英語",

volume = "30",

pages = "2901--2907",

journal = "Japanese Journal of Applied Physics",

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publisher = "Japan Society of Applied Physics",

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TY - JOUR

T1 - Observation and analysis of the Δv=5 stretch overtone band transition of15nh3

AU - Moriwaki, Yoshiki

AU - Nakagawa, Ken’Ichi

AU - Shimizu, Tadao

PY - 1991/11

Y1 - 1991/11

N2 - The absorption spectra of the Δv = 5 stretch overtone band transition of15NH3in the visible region (648 nm band) are observed by the photoacoustic method for the first time. The resolution is 0.01 cm-1. The observed Stark spectra at electric field high enough to resolve M components are helpfully employed in assignment of the rotation and inversion transitions. The vibrational level structure is well explained in terms of the local mode theory. The rotational constants and isotope shift are obtained.

AB - The absorption spectra of the Δv = 5 stretch overtone band transition of15NH3in the visible region (648 nm band) are observed by the photoacoustic method for the first time. The resolution is 0.01 cm-1. The observed Stark spectra at electric field high enough to resolve M components are helpfully employed in assignment of the rotation and inversion transitions. The vibrational level structure is well explained in terms of the local mode theory. The rotational constants and isotope shift are obtained.

KW - Highly excited vibrational state

KW - Local mode vibration

KW - N15ammonia

KW - Overtone band

KW - Photoacoustic spectroscopy

KW - Stark spectroscopy

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U2 - 10.1143/JJAP.30.2901

DO - 10.1143/JJAP.30.2901

M3 - 学術論文

AN - SCOPUS:0026259924

SN - 0021-4922

VL - 30

SP - 2901

EP - 2907

JO - Japanese Journal of Applied Physics

JF - Japanese Journal of Applied Physics

IS - 11R

ER -