Novel intramolecular rearrangement of hepta-coordinate rhenium(V) complex with catecholato and terpyridine ligands

Hideki Sugimoto; Kiyoshi Tsuge; Koji Tanaka

doi:10.1246/cl.1998.719

Novel intramolecular rearrangement of hepta-coordinate rhenium(V) complex with catecholato and terpyridine ligands

Hideki Sugimoto, Kiyoshi Tsuge, Koji Tanaka^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

Novel hepta-coordinate rhenium(V) complex with two 3,6-ditert-butyl-catecholate and one terpyridine ligands was synthesized and structurally characterized. Temperature dependent ¹H NMR spectra reveal dynamic behavior of the complex resulting from the site exchange of an equatrial position between two catecholate ligands.

Original language	English
Pages (from-to)	719-720
Number of pages	2
Journal	Chemistry Letters
Issue number	8
DOIs	https://doi.org/10.1246/cl.1998.719
State	Published - 1998

ASJC Scopus subject areas

General Chemistry

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title = "Novel intramolecular rearrangement of hepta-coordinate rhenium(V) complex with catecholato and terpyridine ligands",

abstract = "Novel hepta-coordinate rhenium(V) complex with two 3,6-ditert-butyl-catecholate and one terpyridine ligands was synthesized and structurally characterized. Temperature dependent 1H NMR spectra reveal dynamic behavior of the complex resulting from the site exchange of an equatrial position between two catecholate ligands.",

author = "Hideki Sugimoto and Kiyoshi Tsuge and Koji Tanaka",

year = "1998",

doi = "10.1246/cl.1998.719",

language = "英語",

pages = "719--720",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "Oxford University Press",

number = "8",

}

TY - JOUR

T1 - Novel intramolecular rearrangement of hepta-coordinate rhenium(V) complex with catecholato and terpyridine ligands

AU - Sugimoto, Hideki

AU - Tsuge, Kiyoshi

AU - Tanaka, Koji

PY - 1998

Y1 - 1998

N2 - Novel hepta-coordinate rhenium(V) complex with two 3,6-ditert-butyl-catecholate and one terpyridine ligands was synthesized and structurally characterized. Temperature dependent 1H NMR spectra reveal dynamic behavior of the complex resulting from the site exchange of an equatrial position between two catecholate ligands.

AB - Novel hepta-coordinate rhenium(V) complex with two 3,6-ditert-butyl-catecholate and one terpyridine ligands was synthesized and structurally characterized. Temperature dependent 1H NMR spectra reveal dynamic behavior of the complex resulting from the site exchange of an equatrial position between two catecholate ligands.

UR - http://www.scopus.com/inward/record.url?scp=0032342795&partnerID=8YFLogxK

U2 - 10.1246/cl.1998.719

DO - 10.1246/cl.1998.719

M3 - 学術論文

AN - SCOPUS:0032342795

SN - 0366-7022

SP - 719

EP - 720

JO - Chemistry Letters

JF - Chemistry Letters

IS - 8

ER -

Novel intramolecular rearrangement of hepta-coordinate rhenium(V) complex with catecholato and terpyridine ligands

Abstract

ASJC Scopus subject areas

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