Luminescence of metal ion-activated nanophosphor supported by nanoporous sol-gel SiO2 matrices

M. Morita; M. Iwamura; D. Rau; M. Itoh; Y. Ishikawa; N. Andoh

doi:10.1016/j.jlumin.2006.01.315

Luminescence of metal ion-activated nanophosphor supported by nanoporous sol-gel SiO₂ matrices

M. Morita^*, M. Iwamura, D. Rau, M. Itoh, Y. Ishikawa, N. Andoh

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

Luminescence of rare-earth ions, transition metal ions and their complexes is investigated to clarify the electronic structure, the electron-lattice interaction, energy migration processes, and nonlinear optical properties of emission centers in nanoporous sol-gel silica glasses. Optical properties of various materials are characterized by measurements of luminescence, excitation spectra, absorption spectra and lifetimes in the temperature range between 10 and 300 K. The nanoporous space is examined by energy transfer in SiO₂:Tb, Cr glasses and CPL properties of Tb(cyclen) complex-doped SiO₂ films. The semiconductor nanocrystals SiO₂/CdS: Eu³⁺ and D-A pair emission of SiO₂/ZnS:Cu, Al, reveal quantum confinement effects in silica hosts: sol-gel SiO₂ glass, films and nanotube MCM 41. For the development of new nanophosphors, surfactants, chemical stability, colors, and porous sizes are discussed in the mesoscopic system.

Original language	English
Pages (from-to)	879-881
Number of pages	3
Journal	Journal of Luminescence
Volume	122-123
Issue number	1-2
DOIs	https://doi.org/10.1016/j.jlumin.2006.01.315
State	Published - 2007/01

Keywords

Al
CdS:Eu
Luminescence
Nanophosphor
Silica SiO
ZnS:Cu

ASJC Scopus subject areas

Biophysics
Biochemistry
General Chemistry
Atomic and Molecular Physics, and Optics
Condensed Matter Physics

Access to Document

10.1016/j.jlumin.2006.01.315

Cite this

@article{a392eec2e5e44b7c98f54523d57b971c,

title = "Luminescence of metal ion-activated nanophosphor supported by nanoporous sol-gel SiO2 matrices",

abstract = "Luminescence of rare-earth ions, transition metal ions and their complexes is investigated to clarify the electronic structure, the electron-lattice interaction, energy migration processes, and nonlinear optical properties of emission centers in nanoporous sol-gel silica glasses. Optical properties of various materials are characterized by measurements of luminescence, excitation spectra, absorption spectra and lifetimes in the temperature range between 10 and 300 K. The nanoporous space is examined by energy transfer in SiO2:Tb, Cr glasses and CPL properties of Tb(cyclen) complex-doped SiO2 films. The semiconductor nanocrystals SiO2/CdS: Eu3+ and D-A pair emission of SiO2/ZnS:Cu, Al, reveal quantum confinement effects in silica hosts: sol-gel SiO2 glass, films and nanotube MCM 41. For the development of new nanophosphors, surfactants, chemical stability, colors, and porous sizes are discussed in the mesoscopic system.",

keywords = "Al, CdS:Eu, Luminescence, Nanophosphor, Silica SiO, ZnS:Cu",

author = "M. Morita and M. Iwamura and D. Rau and M. Itoh and Y. Ishikawa and N. Andoh",

year = "2007",

month = jan,

doi = "10.1016/j.jlumin.2006.01.315",

language = "英語",

volume = "122-123",

pages = "879--881",

journal = "Journal of Luminescence",

issn = "0022-2313",

publisher = "Elsevier B.V.",

number = "1-2",

}

TY - JOUR

T1 - Luminescence of metal ion-activated nanophosphor supported by nanoporous sol-gel SiO2 matrices

AU - Morita, M.

AU - Iwamura, M.

AU - Rau, D.

AU - Itoh, M.

AU - Ishikawa, Y.

AU - Andoh, N.

PY - 2007/1

Y1 - 2007/1

N2 - Luminescence of rare-earth ions, transition metal ions and their complexes is investigated to clarify the electronic structure, the electron-lattice interaction, energy migration processes, and nonlinear optical properties of emission centers in nanoporous sol-gel silica glasses. Optical properties of various materials are characterized by measurements of luminescence, excitation spectra, absorption spectra and lifetimes in the temperature range between 10 and 300 K. The nanoporous space is examined by energy transfer in SiO2:Tb, Cr glasses and CPL properties of Tb(cyclen) complex-doped SiO2 films. The semiconductor nanocrystals SiO2/CdS: Eu3+ and D-A pair emission of SiO2/ZnS:Cu, Al, reveal quantum confinement effects in silica hosts: sol-gel SiO2 glass, films and nanotube MCM 41. For the development of new nanophosphors, surfactants, chemical stability, colors, and porous sizes are discussed in the mesoscopic system.

AB - Luminescence of rare-earth ions, transition metal ions and their complexes is investigated to clarify the electronic structure, the electron-lattice interaction, energy migration processes, and nonlinear optical properties of emission centers in nanoporous sol-gel silica glasses. Optical properties of various materials are characterized by measurements of luminescence, excitation spectra, absorption spectra and lifetimes in the temperature range between 10 and 300 K. The nanoporous space is examined by energy transfer in SiO2:Tb, Cr glasses and CPL properties of Tb(cyclen) complex-doped SiO2 films. The semiconductor nanocrystals SiO2/CdS: Eu3+ and D-A pair emission of SiO2/ZnS:Cu, Al, reveal quantum confinement effects in silica hosts: sol-gel SiO2 glass, films and nanotube MCM 41. For the development of new nanophosphors, surfactants, chemical stability, colors, and porous sizes are discussed in the mesoscopic system.

KW - Al

KW - CdS:Eu

KW - Luminescence

KW - Nanophosphor

KW - Silica SiO

KW - ZnS:Cu

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U2 - 10.1016/j.jlumin.2006.01.315

DO - 10.1016/j.jlumin.2006.01.315

M3 - 学術論文

AN - SCOPUS:33750931221

SN - 0022-2313

VL - 122-123

SP - 879

EP - 881

JO - Journal of Luminescence

JF - Journal of Luminescence

IS - 1-2

ER -