Iron-catalysed oxidation of N,N-(Dialkyl)acylmethylamines with molecular oxygen in the presence of either 2-mercaptoethanol or sodium sulphide

Satoru Murata; Kaoru Suzuki; Masahiro Miura; Masakatsu Nomura

doi:10.1039/p19900000361

Iron-catalysed oxidation of N,N-(Dialkyl)acylmethylamines with molecular oxygen in the presence of either 2-mercaptoethanol or sodium sulphide

Satoru Murata, Kaoru Suzuki, Masahiro Miura^*, Masakatsu Nomura

^*Corresponding author for this work

Department of Art and Design

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

Air-oxidation of N,N-(dialkyl)acylmethylamines (1a-f) using a catalytic amount of [{Fe(salen)}₂O] [salen = N,N′-bis(salicylidene) ethylenediaminato] in the presence of 2-mercaptoethanol gave the corresponding α-oxo amides (2a-f) in moderate to good yields. With sodium sulphide in place of the thiol α-oxo thioamides (9a-f) were obtained as the predominant products.

Original language	English
Pages (from-to)	361-365
Number of pages	5
Journal	Journal of the Chemical Society - Perkin Transactions 1
Issue number	2
DOIs	https://doi.org/10.1039/p19900000361
State	Published - 1990

ASJC Scopus subject areas

General Chemistry

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title = "Iron-catalysed oxidation of N,N-(Dialkyl)acylmethylamines with molecular oxygen in the presence of either 2-mercaptoethanol or sodium sulphide",

abstract = "Air-oxidation of N,N-(dialkyl)acylmethylamines (1a-f) using a catalytic amount of [{Fe(salen)}2O] [salen = N,N′-bis(salicylidene) ethylenediaminato] in the presence of 2-mercaptoethanol gave the corresponding α-oxo amides (2a-f) in moderate to good yields. With sodium sulphide in place of the thiol α-oxo thioamides (9a-f) were obtained as the predominant products.",

author = "Satoru Murata and Kaoru Suzuki and Masahiro Miura and Masakatsu Nomura",

year = "1990",

doi = "10.1039/p19900000361",

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pages = "361--365",

journal = "Journal of the Chemical Society - Perkin Transactions 1",

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T1 - Iron-catalysed oxidation of N,N-(Dialkyl)acylmethylamines with molecular oxygen in the presence of either 2-mercaptoethanol or sodium sulphide

AU - Murata, Satoru

AU - Suzuki, Kaoru

AU - Miura, Masahiro

AU - Nomura, Masakatsu

PY - 1990

Y1 - 1990

N2 - Air-oxidation of N,N-(dialkyl)acylmethylamines (1a-f) using a catalytic amount of [{Fe(salen)}2O] [salen = N,N′-bis(salicylidene) ethylenediaminato] in the presence of 2-mercaptoethanol gave the corresponding α-oxo amides (2a-f) in moderate to good yields. With sodium sulphide in place of the thiol α-oxo thioamides (9a-f) were obtained as the predominant products.

AB - Air-oxidation of N,N-(dialkyl)acylmethylamines (1a-f) using a catalytic amount of [{Fe(salen)}2O] [salen = N,N′-bis(salicylidene) ethylenediaminato] in the presence of 2-mercaptoethanol gave the corresponding α-oxo amides (2a-f) in moderate to good yields. With sodium sulphide in place of the thiol α-oxo thioamides (9a-f) were obtained as the predominant products.

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DO - 10.1039/p19900000361

M3 - 学術論文

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JO - Journal of the Chemical Society - Perkin Transactions 1

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IS - 2

ER -

Iron-catalysed oxidation of N,N-(Dialkyl)acylmethylamines with molecular oxygen in the presence of either 2-mercaptoethanol or sodium sulphide

Abstract

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