Intramolecular reductive nitrosylation: Reaction of nitric oxide and a copper(II) comprex of a cyclam derivative with pendant luminescent chromophores

Kiyoshi Tsuge; Frank DeRosa; Mark D. Lim; Peter C. Ford

doi:10.1021/ja049444b

Intramolecular reductive nitrosylation: Reaction of nitric oxide and a copper(II) comprex of a cyclam derivative with pendant luminescent chromophores

Kiyoshi Tsuge, Frank DeRosa, Mark D. Lim, Peter C. Ford^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

108 Scopus citations

Abstract

The base-catalyzed reaction of nitric oxide with the Cu(II) complex Cu(DAC)²⁺ (DAC = 1,8-bis(9-anthracyl-methyl)-(1,4,8,11-tetraazacyclotetradecane)) leads to reduction of the metal center and the unexpected intramolecular nitrosylation of a secondary amine.

Original language	English
Pages (from-to)	6564-6565
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	126
Issue number	21
DOIs	https://doi.org/10.1021/ja049444b
State	Published - 2004/06/02

ASJC Scopus subject areas

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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title = "Intramolecular reductive nitrosylation: Reaction of nitric oxide and a copper(II) comprex of a cyclam derivative with pendant luminescent chromophores",

abstract = "The base-catalyzed reaction of nitric oxide with the Cu(II) complex Cu(DAC)2+ (DAC = 1,8-bis(9-anthracyl-methyl)-(1,4,8,11-tetraazacyclotetradecane)) leads to reduction of the metal center and the unexpected intramolecular nitrosylation of a secondary amine.",

author = "Kiyoshi Tsuge and Frank DeRosa and Lim, {Mark D.} and Ford, {Peter C.}",

year = "2004",

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T1 - Intramolecular reductive nitrosylation

T2 - Reaction of nitric oxide and a copper(II) comprex of a cyclam derivative with pendant luminescent chromophores

AU - Tsuge, Kiyoshi

AU - DeRosa, Frank

AU - Lim, Mark D.

AU - Ford, Peter C.

PY - 2004/6/2

Y1 - 2004/6/2

N2 - The base-catalyzed reaction of nitric oxide with the Cu(II) complex Cu(DAC)2+ (DAC = 1,8-bis(9-anthracyl-methyl)-(1,4,8,11-tetraazacyclotetradecane)) leads to reduction of the metal center and the unexpected intramolecular nitrosylation of a secondary amine.

AB - The base-catalyzed reaction of nitric oxide with the Cu(II) complex Cu(DAC)2+ (DAC = 1,8-bis(9-anthracyl-methyl)-(1,4,8,11-tetraazacyclotetradecane)) leads to reduction of the metal center and the unexpected intramolecular nitrosylation of a secondary amine.

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U2 - 10.1021/ja049444b

DO - 10.1021/ja049444b

M3 - 学術論文

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AN - SCOPUS:2542576197

SN - 0002-7863

VL - 126

SP - 6564

EP - 6565

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 21

ER -

Intramolecular reductive nitrosylation: Reaction of nitric oxide and a copper(II) comprex of a cyclam derivative with pendant luminescent chromophores

Abstract

ASJC Scopus subject areas

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