Hyperfine-structure-induced purely long-range molecules

Katsunari Enomoto*, Masaaki Kitagawa, Satoshi Tojo, Yoshiro Takahashi

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

27 Scopus citations

Abstract

We have experimentally observed and theoretically identified a novel class of purely long-range molecules. This novel purely long-range state is formed due to a very weak hyperfine interaction that is usually treated only as a small perturbation in molecular spectra. Photoassociation spectroscopy of ultracold ytterbium (Yb171) atoms with the S01-P13 intercombination transition presents clear identification of molecular states and the shallowest molecular potential depth of about 750 MHz among the purely long-range molecules ever observed.

Original languageEnglish
Article number123001
JournalPhysical Review Letters
Volume100
Issue number12
DOIs
StatePublished - 2008/03/24

ASJC Scopus subject areas

  • General Physics and Astronomy

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