Highly stereoselective synthesis of 2-methyl-1,3-dienes by palladium-catalyzed cross-coupling reaction with trimethylaluminum

Masahiro Miyazawa; Risa Takehana; Takao Sanga; Aoi Hosomori; Hajime Yokoyama; Yoshiro Hirai

doi:10.1055/s-0033-1340477

Highly stereoselective synthesis of 2-methyl-1,3-dienes by palladium-catalyzed cross-coupling reaction with trimethylaluminum

Masahiro Miyazawa^*, Risa Takehana, Takao Sanga, Aoi Hosomori, Hajime Yokoyama, Yoshiro Hirai

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Palladium-catalyzed cross-coupling reaction using tricyclohexylphosphine can be used to convert a range of 2-bromo-1,3-dienes efficiently and selectively to the corresponding methyl-branched conjugated dienes.

Original language	English
Article number	ST-2013-U0962-L
Pages (from-to)	531-534
Number of pages	4
Journal	Synlett
Volume	25
Issue number	4
DOIs	https://doi.org/10.1055/s-0033-1340477
State	Published - 2014/03

Keywords

alkylation
conjugated diene
cross-coupling
isomerization
palladium catalyst

ASJC Scopus subject areas

Organic Chemistry
Drug Discovery

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10.1055/s-0033-1340477

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title = "Highly stereoselective synthesis of 2-methyl-1,3-dienes by palladium-catalyzed cross-coupling reaction with trimethylaluminum",

abstract = "Palladium-catalyzed cross-coupling reaction using tricyclohexylphosphine can be used to convert a range of 2-bromo-1,3-dienes efficiently and selectively to the corresponding methyl-branched conjugated dienes.",

keywords = "alkylation, conjugated diene, cross-coupling, isomerization, palladium catalyst",

author = "Masahiro Miyazawa and Risa Takehana and Takao Sanga and Aoi Hosomori and Hajime Yokoyama and Yoshiro Hirai",

year = "2014",

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doi = "10.1055/s-0033-1340477",

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pages = "531--534",

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T1 - Highly stereoselective synthesis of 2-methyl-1,3-dienes by palladium-catalyzed cross-coupling reaction with trimethylaluminum

AU - Miyazawa, Masahiro

AU - Takehana, Risa

AU - Sanga, Takao

AU - Hosomori, Aoi

AU - Yokoyama, Hajime

AU - Hirai, Yoshiro

PY - 2014/3

Y1 - 2014/3

N2 - Palladium-catalyzed cross-coupling reaction using tricyclohexylphosphine can be used to convert a range of 2-bromo-1,3-dienes efficiently and selectively to the corresponding methyl-branched conjugated dienes.

AB - Palladium-catalyzed cross-coupling reaction using tricyclohexylphosphine can be used to convert a range of 2-bromo-1,3-dienes efficiently and selectively to the corresponding methyl-branched conjugated dienes.

KW - alkylation

KW - conjugated diene

KW - cross-coupling

KW - isomerization

KW - palladium catalyst

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U2 - 10.1055/s-0033-1340477

DO - 10.1055/s-0033-1340477

M3 - 学術論文

AN - SCOPUS:84896738586

SN - 0936-5214

VL - 25

SP - 531

EP - 534

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ER -

Highly stereoselective synthesis of 2-methyl-1,3-dienes by palladium-catalyzed cross-coupling reaction with trimethylaluminum

Abstract

Keywords

ASJC Scopus subject areas

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