High-resolution electronic spectroscopy of buffer-gas-cooled metal-phthalocyanines

Yuki Miyamoto; Masaaki Baba; Katsunari Enomoto; Ayami Hiramoto; Kana Iwakuni; Susumu Kuma

High-resolution electronic spectroscopy of buffer-gas-cooled metal-phthalocyanines

Yuki Miyamoto^*, Masaaki Baba, Katsunari Enomoto, Ayami Hiramoto, Kana Iwakuni, Susumu Kuma

^*Corresponding author for this work

Program of Physics

Research output: Contribution to journal › Article › peer-review

Abstract

High-resolution absorption spectra of the S₁ ← S₀ 0₀⁰ transition of buffer-gas-cooled magnesium-phthalocyanine, zinc-phthalocyanine, and chloroaluminum-phthalocyanine are presented. The low temperature achieved through buffer gas cooling allowed the observation of a partially resolved rotational structure in each spectrum. We compare these structures with the previously observed high-resolution spectrum of free-base phthalocyanine. Despite the similar molecular structures of these molecules, the spectral characteristics of the rotational envelope vary depending on the individual molecular structures.

Original language	English
Pages (from-to)	897-901
Number of pages	5
Journal	Fizika Nizkikh Temperatur
Volume	50
Issue number	9
State	Published - 2024

Keywords

absorption spectra
excited states
high-resolution electronic spectroscopy
metal-phthalocyanine
phthalocyanine

ASJC Scopus subject areas

General Physics and Astronomy

Cite this

@article{ad4501ee59f04313a5c7bc7962acbbac,

title = "High-resolution electronic spectroscopy of buffer-gas-cooled metal-phthalocyanines",

abstract = "High-resolution absorption spectra of the S1 ← S0 000 transition of buffer-gas-cooled magnesium-phthalocyanine, zinc-phthalocyanine, and chloroaluminum-phthalocyanine are presented. The low temperature achieved through buffer gas cooling allowed the observation of a partially resolved rotational structure in each spectrum. We compare these structures with the previously observed high-resolution spectrum of free-base phthalocyanine. Despite the similar molecular structures of these molecules, the spectral characteristics of the rotational envelope vary depending on the individual molecular structures.",

keywords = "absorption spectra, excited states, high-resolution electronic spectroscopy, metal-phthalocyanine, phthalocyanine",

author = "Yuki Miyamoto and Masaaki Baba and Katsunari Enomoto and Ayami Hiramoto and Kana Iwakuni and Susumu Kuma",

note = "Publisher Copyright: {\textcopyright} Yuki Miyamoto, Masaaki Baba, Katsunari Enomoto, Ayami Hiramoto, Kana Iwakuni, and Susumu Kuma, 2024.",

year = "2024",

language = "英語",

volume = "50",

pages = "897--901",

journal = "Fizika Nizkikh Temperatur",

issn = "0132-6414",

publisher = "ILTPE-B. Verkin Institute for Low Temperature Physics and Engineering",

number = "9",

}

TY - JOUR

T1 - High-resolution electronic spectroscopy of buffer-gas-cooled metal-phthalocyanines

AU - Miyamoto, Yuki

AU - Baba, Masaaki

AU - Enomoto, Katsunari

AU - Hiramoto, Ayami

AU - Iwakuni, Kana

AU - Kuma, Susumu

N1 - Publisher Copyright: © Yuki Miyamoto, Masaaki Baba, Katsunari Enomoto, Ayami Hiramoto, Kana Iwakuni, and Susumu Kuma, 2024.

PY - 2024

Y1 - 2024

N2 - High-resolution absorption spectra of the S1 ← S0 000 transition of buffer-gas-cooled magnesium-phthalocyanine, zinc-phthalocyanine, and chloroaluminum-phthalocyanine are presented. The low temperature achieved through buffer gas cooling allowed the observation of a partially resolved rotational structure in each spectrum. We compare these structures with the previously observed high-resolution spectrum of free-base phthalocyanine. Despite the similar molecular structures of these molecules, the spectral characteristics of the rotational envelope vary depending on the individual molecular structures.

AB - High-resolution absorption spectra of the S1 ← S0 000 transition of buffer-gas-cooled magnesium-phthalocyanine, zinc-phthalocyanine, and chloroaluminum-phthalocyanine are presented. The low temperature achieved through buffer gas cooling allowed the observation of a partially resolved rotational structure in each spectrum. We compare these structures with the previously observed high-resolution spectrum of free-base phthalocyanine. Despite the similar molecular structures of these molecules, the spectral characteristics of the rotational envelope vary depending on the individual molecular structures.

KW - absorption spectra

KW - excited states

KW - high-resolution electronic spectroscopy

KW - metal-phthalocyanine

KW - phthalocyanine

UR - http://www.scopus.com/inward/record.url?scp=85202294703&partnerID=8YFLogxK

M3 - 学術論文

AN - SCOPUS:85202294703

SN - 0132-6414

VL - 50

SP - 897

EP - 901

JO - Fizika Nizkikh Temperatur

JF - Fizika Nizkikh Temperatur

IS - 9

ER -

High-resolution electronic spectroscopy of buffer-gas-cooled metal-phthalocyanines

Abstract

Keywords

ASJC Scopus subject areas

Fingerprint

Cite this