High-resolution electronic spectroscopy of buffer-gas-cooled metal-phthalocyanines

Yuki Miyamoto; Masaaki Baba; Katsunari Enomoto; Ayami Hiramoto; Kana Iwakuni; Susumu Kuma

doi:10.1063/10.0028188

High-resolution electronic spectroscopy of buffer-gas-cooled metal-phthalocyanines

Yuki Miyamoto^*, Masaaki Baba, Katsunari Enomoto, Ayami Hiramoto, Kana Iwakuni, Susumu Kuma

^*Corresponding author for this work

Program of Physics

Research output: Contribution to journal › Article › peer-review

Abstract

High-resolution absorption spectra of the S 1 ← S 0 0 0 0 transition of buffer-gas-cooled magnesium-phthalocyanine, zinc-phthalocyanine, and chloroaluminum-phthalocyanine are presented. The low temperature achieved through buffer gas cooling allowed the observation of a partially resolved rotational structure in each spectrum. We compare these structures with the previously observed high-resolution spectrum of free-base phthalocyanine. Despite the similar molecular structures of these molecules, the spectral characteristics of the rotational envelope vary depending on the individual molecular structures.

Original language	English
Pages (from-to)	808-812
Number of pages	5
Journal	Low Temperature Physics
Volume	50
Issue number	9
DOIs	https://doi.org/10.1063/10.0028188
State	Published - 2024/09/01

Keywords

absorption spectra
excited states.
high-resolution electronic spectroscopy
metal-phthalocyanine
phthalocyanine

ASJC Scopus subject areas

Physics and Astronomy (miscellaneous)

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10.1063/10.0028188

Cite this

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title = "High-resolution electronic spectroscopy of buffer-gas-cooled metal-phthalocyanines",

abstract = "High-resolution absorption spectra of the S 1 ← S 0 0 0 0 transition of buffer-gas-cooled magnesium-phthalocyanine, zinc-phthalocyanine, and chloroaluminum-phthalocyanine are presented. The low temperature achieved through buffer gas cooling allowed the observation of a partially resolved rotational structure in each spectrum. We compare these structures with the previously observed high-resolution spectrum of free-base phthalocyanine. Despite the similar molecular structures of these molecules, the spectral characteristics of the rotational envelope vary depending on the individual molecular structures.",

keywords = "absorption spectra, excited states., high-resolution electronic spectroscopy, metal-phthalocyanine, phthalocyanine",

author = "Yuki Miyamoto and Masaaki Baba and Katsunari Enomoto and Ayami Hiramoto and Kana Iwakuni and Susumu Kuma",

note = "Publisher Copyright: {\textcopyright} 2024 Author(s).",

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doi = "10.1063/10.0028188",

language = "英語",

volume = "50",

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T1 - High-resolution electronic spectroscopy of buffer-gas-cooled metal-phthalocyanines

AU - Miyamoto, Yuki

AU - Baba, Masaaki

AU - Enomoto, Katsunari

AU - Hiramoto, Ayami

AU - Iwakuni, Kana

AU - Kuma, Susumu

PY - 2024/9/1

Y1 - 2024/9/1

N2 - High-resolution absorption spectra of the S 1 ← S 0 0 0 0 transition of buffer-gas-cooled magnesium-phthalocyanine, zinc-phthalocyanine, and chloroaluminum-phthalocyanine are presented. The low temperature achieved through buffer gas cooling allowed the observation of a partially resolved rotational structure in each spectrum. We compare these structures with the previously observed high-resolution spectrum of free-base phthalocyanine. Despite the similar molecular structures of these molecules, the spectral characteristics of the rotational envelope vary depending on the individual molecular structures.

AB - High-resolution absorption spectra of the S 1 ← S 0 0 0 0 transition of buffer-gas-cooled magnesium-phthalocyanine, zinc-phthalocyanine, and chloroaluminum-phthalocyanine are presented. The low temperature achieved through buffer gas cooling allowed the observation of a partially resolved rotational structure in each spectrum. We compare these structures with the previously observed high-resolution spectrum of free-base phthalocyanine. Despite the similar molecular structures of these molecules, the spectral characteristics of the rotational envelope vary depending on the individual molecular structures.

KW - absorption spectra

KW - excited states.

KW - high-resolution electronic spectroscopy

KW - metal-phthalocyanine

KW - phthalocyanine

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DO - 10.1063/10.0028188

M3 - 学術論文

AN - SCOPUS:85203292160

SN - 1063-777X

VL - 50

SP - 808

EP - 812

JO - Low Temperature Physics

JF - Low Temperature Physics

IS - 9

ER -

High-resolution electronic spectroscopy of buffer-gas-cooled metal-phthalocyanines

Abstract

Keywords

ASJC Scopus subject areas

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