Fixation of carbon dioxide with 1,2-epoxypropane catalysed by tetra-t-butylphthalocyaninatoaluminium(III) acetate, tetra-t-butylphthalocyaninatoaluminium(III) trimethylsilanolate and tetra-t-butylphthalocyaninatoaluminium (III) triphenylsilanolate

Kuninobu Kasuga; Naohiko Kabata; Takao Kato; Tamotsu Sugimori; Makoto Handa

doi:10.1016/S0020-1693(98)00015-2

Fixation of carbon dioxide with 1,2-epoxypropane catalysed by tetra-t-butylphthalocyaninatoaluminium(III) acetate, tetra-t-butylphthalocyaninatoaluminium(III) trimethylsilanolate and tetra-t-butylphthalocyaninatoaluminium (III) triphenylsilanolate

Kuninobu Kasuga^*, Naohiko Kabata, Takao Kato, Tamotsu Sugimori, Makoto Handa

^*Corresponding author for this work

Faculty of Liberal Arts and Sciences

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

The chemical fixation of carbon dioxide with 1,2-epoxypropane was catalysed by tetra-t-butylphthalocyaninatoaluminiura(III) acetate, tetra-t-butylphthalocyaninatoaluminium(III) trimethylsilanolate and tetra-t-butylphthalocyaninatoaluminium(III) triphenylsilanolate in the presence of tetrabutylammonium iodide or triethyl (2-hydroxypropyl) ammonium iodide at room temperature. Propane-1,2-diol carbonate was prepared from carbon dioxide and 1,2-epoxypropane via a six-membered ring-intermediate. Depending on an axial ligand of the complex, the fixation proceeded via an hexacoordinated intermediate (for the complex with chloride or hydroxide as the axial ligand) or a six-membered ring-intermediate (for the complex with acetate or silanolate).

Original language	English
Pages (from-to)	223-225
Number of pages	3
Journal	Inorganica Chimica Acta
Volume	278
Issue number	2
DOIs	https://doi.org/10.1016/S0020-1693(98)00015-2
State	Published - 1998/09/01

Keywords

Aluminium complexes
Carbon dioxide fixation
Phthalocyanine complexes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S0020-1693(98)00015-2

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Kasuga, K., Kabata, N., Kato, T., Sugimori, T., & Handa, M. (1998). Fixation of carbon dioxide with 1,2-epoxypropane catalysed by tetra-t-butylphthalocyaninatoaluminium(III) acetate, tetra-t-butylphthalocyaninatoaluminium(III) trimethylsilanolate and tetra-t-butylphthalocyaninatoaluminium (III) triphenylsilanolate. Inorganica Chimica Acta, 278(2), 223-225. https://doi.org/10.1016/S0020-1693(98)00015-2

Kasuga, Kuninobu ; Kabata, Naohiko ; Kato, Takao et al. / Fixation of carbon dioxide with 1,2-epoxypropane catalysed by tetra-t-butylphthalocyaninatoaluminium(III) acetate, tetra-t-butylphthalocyaninatoaluminium(III) trimethylsilanolate and tetra-t-butylphthalocyaninatoaluminium (III) triphenylsilanolate. In: Inorganica Chimica Acta. 1998 ; Vol. 278, No. 2. pp. 223-225.

@article{fc7c2843c1464f0fa78ed3f34fcfdb5c,

title = "Fixation of carbon dioxide with 1,2-epoxypropane catalysed by tetra-t-butylphthalocyaninatoaluminium(III) acetate, tetra-t-butylphthalocyaninatoaluminium(III) trimethylsilanolate and tetra-t-butylphthalocyaninatoaluminium (III) triphenylsilanolate",

abstract = "The chemical fixation of carbon dioxide with 1,2-epoxypropane was catalysed by tetra-t-butylphthalocyaninatoaluminiura(III) acetate, tetra-t-butylphthalocyaninatoaluminium(III) trimethylsilanolate and tetra-t-butylphthalocyaninatoaluminium(III) triphenylsilanolate in the presence of tetrabutylammonium iodide or triethyl (2-hydroxypropyl) ammonium iodide at room temperature. Propane-1,2-diol carbonate was prepared from carbon dioxide and 1,2-epoxypropane via a six-membered ring-intermediate. Depending on an axial ligand of the complex, the fixation proceeded via an hexacoordinated intermediate (for the complex with chloride or hydroxide as the axial ligand) or a six-membered ring-intermediate (for the complex with acetate or silanolate).",

keywords = "Aluminium complexes, Carbon dioxide fixation, Phthalocyanine complexes",

author = "Kuninobu Kasuga and Naohiko Kabata and Takao Kato and Tamotsu Sugimori and Makoto Handa",

note = "Funding Information: This work was supported by a Grant-in-Aid for Scientific Research No. 09640668 from the Ministry of Education, Sei-ence, Sports and Culture and by a grant from the Electric Technology Research Foundation of Chugoku.",

year = "1998",

month = sep,

day = "1",

doi = "10.1016/S0020-1693(98)00015-2",

language = "英語",

volume = "278",

pages = "223--225",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier B.V.",

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Kasuga, K, Kabata, N, Kato, T, Sugimori, T & Handa, M 1998, 'Fixation of carbon dioxide with 1,2-epoxypropane catalysed by tetra-t-butylphthalocyaninatoaluminium(III) acetate, tetra-t-butylphthalocyaninatoaluminium(III) trimethylsilanolate and tetra-t-butylphthalocyaninatoaluminium (III) triphenylsilanolate', Inorganica Chimica Acta, vol. 278, no. 2, pp. 223-225. https://doi.org/10.1016/S0020-1693(98)00015-2

Fixation of carbon dioxide with 1,2-epoxypropane catalysed by tetra-t-butylphthalocyaninatoaluminium(III) acetate, tetra-t-butylphthalocyaninatoaluminium(III) trimethylsilanolate and tetra-t-butylphthalocyaninatoaluminium (III) triphenylsilanolate. / Kasuga, Kuninobu; Kabata, Naohiko; Kato, Takao et al.
In: Inorganica Chimica Acta, Vol. 278, No. 2, 01.09.1998, p. 223-225.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Fixation of carbon dioxide with 1,2-epoxypropane catalysed by tetra-t-butylphthalocyaninatoaluminium(III) acetate, tetra-t-butylphthalocyaninatoaluminium(III) trimethylsilanolate and tetra-t-butylphthalocyaninatoaluminium (III) triphenylsilanolate

AU - Kasuga, Kuninobu

AU - Kabata, Naohiko

AU - Kato, Takao

AU - Sugimori, Tamotsu

AU - Handa, Makoto

N1 - Funding Information: This work was supported by a Grant-in-Aid for Scientific Research No. 09640668 from the Ministry of Education, Sei-ence, Sports and Culture and by a grant from the Electric Technology Research Foundation of Chugoku.

PY - 1998/9/1

Y1 - 1998/9/1

N2 - The chemical fixation of carbon dioxide with 1,2-epoxypropane was catalysed by tetra-t-butylphthalocyaninatoaluminiura(III) acetate, tetra-t-butylphthalocyaninatoaluminium(III) trimethylsilanolate and tetra-t-butylphthalocyaninatoaluminium(III) triphenylsilanolate in the presence of tetrabutylammonium iodide or triethyl (2-hydroxypropyl) ammonium iodide at room temperature. Propane-1,2-diol carbonate was prepared from carbon dioxide and 1,2-epoxypropane via a six-membered ring-intermediate. Depending on an axial ligand of the complex, the fixation proceeded via an hexacoordinated intermediate (for the complex with chloride or hydroxide as the axial ligand) or a six-membered ring-intermediate (for the complex with acetate or silanolate).

AB - The chemical fixation of carbon dioxide with 1,2-epoxypropane was catalysed by tetra-t-butylphthalocyaninatoaluminiura(III) acetate, tetra-t-butylphthalocyaninatoaluminium(III) trimethylsilanolate and tetra-t-butylphthalocyaninatoaluminium(III) triphenylsilanolate in the presence of tetrabutylammonium iodide or triethyl (2-hydroxypropyl) ammonium iodide at room temperature. Propane-1,2-diol carbonate was prepared from carbon dioxide and 1,2-epoxypropane via a six-membered ring-intermediate. Depending on an axial ligand of the complex, the fixation proceeded via an hexacoordinated intermediate (for the complex with chloride or hydroxide as the axial ligand) or a six-membered ring-intermediate (for the complex with acetate or silanolate).

KW - Aluminium complexes

KW - Carbon dioxide fixation

KW - Phthalocyanine complexes

UR - http://www.scopus.com/inward/record.url?scp=0040005744&partnerID=8YFLogxK

U2 - 10.1016/S0020-1693(98)00015-2

DO - 10.1016/S0020-1693(98)00015-2

M3 - 学術論文

AN - SCOPUS:0040005744

SN - 0020-1693

VL - 278

SP - 223

EP - 225

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 2

ER -

Kasuga K, Kabata N, Kato T, Sugimori T, Handa M. Fixation of carbon dioxide with 1,2-epoxypropane catalysed by tetra-t-butylphthalocyaninatoaluminium(III) acetate, tetra-t-butylphthalocyaninatoaluminium(III) trimethylsilanolate and tetra-t-butylphthalocyaninatoaluminium (III) triphenylsilanolate. Inorganica Chimica Acta. 1998 Sep 1;278(2):223-225. doi: 10.1016/S0020-1693(98)00015-2