Electrochemical reduction of carbon dioxide catalysed by macrocyclic Fe4S4 iron-sulphur clusters

Takenori Tomohiro; Kouichi Uoto; Hiroaki Okuno

doi:10.1039/C39900000194

Electrochemical reduction of carbon dioxide catalysed by macrocyclic Fe₄S₄ iron-sulphur clusters

Takenori Tomohiro, Kouichi Uoto, Hiroaki Okuno^*

^*Corresponding author for this work

Biorecognition Chemistry

Research output: Contribution to journal › Article › peer-review

32 Scopus citations

Abstract

Electrochemical fixation of CO₂ into formate was efficiently carried out by using Fe₄S₄ cubane clusters bearing a 36-membered methylene backbone in dimethylformamide with initial current efficiencies of 40 and 23%, respectively, for t-butyl and benzyl type macrocyclic Fe-S derivatives; these derivatives are several times more efficient than conventional clusters bearing small thiolate ligands.

Original language	English
Pages (from-to)	194-195
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	2
DOIs	https://doi.org/10.1039/C39900000194
State	Published - 1990

ASJC Scopus subject areas

Molecular Medicine

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10.1039/C39900000194

Cite this

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title = "Electrochemical reduction of carbon dioxide catalysed by macrocyclic Fe4S4 iron-sulphur clusters",

abstract = "Electrochemical fixation of CO2 into formate was efficiently carried out by using Fe4S4 cubane clusters bearing a 36-membered methylene backbone in dimethylformamide with initial current efficiencies of 40 and 23%, respectively, for t-butyl and benzyl type macrocyclic Fe-S derivatives; these derivatives are several times more efficient than conventional clusters bearing small thiolate ligands.",

author = "Takenori Tomohiro and Kouichi Uoto and Hiroaki Okuno",

year = "1990",

doi = "10.1039/C39900000194",

language = "英語",

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journal = "Journal of the Chemical Society, Chemical Communications",

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publisher = "Chemical Society",

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T1 - Electrochemical reduction of carbon dioxide catalysed by macrocyclic Fe4S4 iron-sulphur clusters

AU - Tomohiro, Takenori

AU - Uoto, Kouichi

AU - Okuno, Hiroaki

PY - 1990

Y1 - 1990

N2 - Electrochemical fixation of CO2 into formate was efficiently carried out by using Fe4S4 cubane clusters bearing a 36-membered methylene backbone in dimethylformamide with initial current efficiencies of 40 and 23%, respectively, for t-butyl and benzyl type macrocyclic Fe-S derivatives; these derivatives are several times more efficient than conventional clusters bearing small thiolate ligands.

AB - Electrochemical fixation of CO2 into formate was efficiently carried out by using Fe4S4 cubane clusters bearing a 36-membered methylene backbone in dimethylformamide with initial current efficiencies of 40 and 23%, respectively, for t-butyl and benzyl type macrocyclic Fe-S derivatives; these derivatives are several times more efficient than conventional clusters bearing small thiolate ligands.

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U2 - 10.1039/C39900000194

DO - 10.1039/C39900000194

M3 - 学術論文

AN - SCOPUS:37049079630

SN - 0022-4936

SP - 194

EP - 195

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 2