@inproceedings{4725e2fac0154e7ea0ec55a4e3847f7f,
title = "Electrochemical formation of Tb alloys in LiCl-KCl eutectic melts",
abstract = "The electrochemical formation of Tb-Ni alloys was investigated in a molten LiCl-KCl-TbCl3(0.50 mol% added) at 723 K. Open-circuit potentiometry was conducted using a Ni electrode after electrodepositing Tb metal at 0.20 V (vs. Li+ / Li) for 300 s. There were four potential plateaus at (a) 0.66 V, (b) 0.80 V, (c) 0.95 V and (d) 1.56 V, respectively. Alloy samples were prepared by potentiostatic electrolysis at 0.60 V and 0.70 V at 723 K. The alloy phase was identified as only TbNi2. Anodic dissolution of Tb from the formed TbNi2 was conducted at 0.90 V, 1.20 V and 1.60 V, respectively. In the sample obtained at 0.90 V for 3 h, the existence of TbNi3 was identified by the XRD. Phase of the sample obtained at 1.20 V for 3 h was TbNi5. The sample obtained at 1.60 V for 3 h was Ni.",
keywords = "Electrolysis, Molten salt, Rare earth, Separation",
author = "Hirokazu Konishi and Kenta Mizuma and Hideki Ono and Eiichi Takeuchi and Toshiyuki Nohira and Tetsuo Oishi",
year = "2013",
doi = "10.1007/978-3-319-48764-9_35",
language = "英語",
isbn = "9781632660008",
series = "8th Pacific Rim International Congress on Advanced Materials and Processing 2013, PRICM 8",
publisher = "John Wiley and Sons Inc.",
pages = "277--285",
booktitle = "8th Pacific Rim International Congress on Advanced Materials and Processing 2013, PRICM 8",
note = "8th Pacific Rim International Congress on Advanced Materials and Processing 2013, PRICM 8 ; Conference date: 04-08-2013 Through 09-08-2013",
}