Double addition of CO2 and CH3OH to ruthenium carbonyl complex with novel monodentate dithiolene

Hideki Sugimoto, Kiyoshi Tsuge, Koji Tanaka*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

2 Scopus citations

Abstract

A ruthenium carbonyl complex with unique monodentate SSC2(CN)22- was prepared, while analogous SSC2Ph22- derivative underwent electrophilic and nucleophilic attacks of CO2 and CH3OH to the thiolato and the CO ligands to produce the Ru complex with thio-carboxylic acid and methoxy carbonyl units.

Original languageEnglish
Pages (from-to)1007-1008
Number of pages2
JournalChemistry Letters
Issue number10
DOIs
StatePublished - 1999

ASJC Scopus subject areas

  • General Chemistry

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