Doppler effect in fragment autoionization following core-to-Rydberg excitations of N2

Eiji Shigemasa*, Tatsuo Kaneyasu, Tomohiro Matsushita, Yusuke Tamenori, Yasumasa Hikosaka

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

10 Scopus citations

Abstract

The autoionization of atomic fragments after core-to-Rydberg excitations in N2 has been studied using high-resolution electron spectroscopy. Doppler profiles are clearly observed on atomic autoionization peaks and show dependence on the symmetries of the excited states. It is demonstrated that information on the femtosecond dissociation dynamics after the Rydberg excitations can be gained through an analysis of the Doppler profiles.

Original languageEnglish
Article number063030
JournalNew Journal of Physics
Volume12
DOIs
StatePublished - 2010/06/16

ASJC Scopus subject areas

  • General Physics and Astronomy

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