Crystal structure of S-octyl (E)-3-(4-methoxybenzylidene) dithiocarbazate

M. S. Begum; E. Zangrando; M. C. Sheikh; R. Miyatake; M. M. Hossain; C. Rizzoli

doi:10.1107/S205698901500568X

Crystal structure of S-octyl (E)-3-(4-methoxybenzylidene) dithiocarbazate

M. S. Begum^*, E. Zangrando, M. C. Sheikh, R. Miyatake, M. M. Hossain, C. Rizzoli

^*Corresponding author for this work

Center for Environmental Conservation and Research Safety

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

As already observed in similar molecules, the dithiocarbazate group in the title compound, C₁₇H₂₆N₂OS₂, adopts an EE configuration with respect to the C=N bond of the benzyl-idene moiety. In the crystal, molecules are connected into inversion dimers by pairs of N - H⋯S hydrogen bonds. The dimers are linked by weak π-π interactions, with centroid-to-centroid distances of 3.723 (11) Å, forming chains parallel to [110].

Original language	English
Pages (from-to)	o265-o266
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	71
Issue number	4
DOIs	https://doi.org/10.1107/S205698901500568X
State	Published - 2015/04/01

Keywords

Crystal structure
Dithiocarbazate
Hydrogen bonding
S-containing Schiff bases

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "Crystal structure of S-octyl (E)-3-(4-methoxybenzylidene) dithiocarbazate",

abstract = "As already observed in similar molecules, the dithiocarbazate group in the title compound, C17H26N2OS2, adopts an EE configuration with respect to the C=N bond of the benzyl-idene moiety. In the crystal, molecules are connected into inversion dimers by pairs of N - H⋯S hydrogen bonds. The dimers are linked by weak π-π interactions, with centroid-to-centroid distances of 3.723 (11) {\AA}, forming chains parallel to [110].",

keywords = "Crystal structure, Dithiocarbazate, Hydrogen bonding, S-containing Schiff bases",

author = "Begum, {M. S.} and E. Zangrando and Sheikh, {M. C.} and R. Miyatake and Hossain, {M. M.} and C. Rizzoli",

year = "2015",

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doi = "10.1107/S205698901500568X",

language = "英語",

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publisher = "International Union of Crystallography",

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TY - JOUR

T1 - Crystal structure of S-octyl (E)-3-(4-methoxybenzylidene) dithiocarbazate

AU - Begum, M. S.

AU - Zangrando, E.

AU - Sheikh, M. C.

AU - Miyatake, R.

AU - Hossain, M. M.

AU - Rizzoli, C.

PY - 2015/4/1

Y1 - 2015/4/1

N2 - As already observed in similar molecules, the dithiocarbazate group in the title compound, C17H26N2OS2, adopts an EE configuration with respect to the C=N bond of the benzyl-idene moiety. In the crystal, molecules are connected into inversion dimers by pairs of N - H⋯S hydrogen bonds. The dimers are linked by weak π-π interactions, with centroid-to-centroid distances of 3.723 (11) Å, forming chains parallel to [110].

AB - As already observed in similar molecules, the dithiocarbazate group in the title compound, C17H26N2OS2, adopts an EE configuration with respect to the C=N bond of the benzyl-idene moiety. In the crystal, molecules are connected into inversion dimers by pairs of N - H⋯S hydrogen bonds. The dimers are linked by weak π-π interactions, with centroid-to-centroid distances of 3.723 (11) Å, forming chains parallel to [110].

KW - Crystal structure

KW - Dithiocarbazate

KW - Hydrogen bonding

KW - S-containing Schiff bases

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DO - 10.1107/S205698901500568X

M3 - 学術論文

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AN - SCOPUS:84928159196

SN - 1600-5368

VL - 71

SP - o265-o266

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 4

ER -

Crystal structure of S-octyl (E)-3-(4-methoxybenzylidene) dithiocarbazate

Abstract

Keywords

ASJC Scopus subject areas

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