Crystal structure of S-hexyl (E)-3-(4-methylbenzylidene)dithiocarbazate

M. B.H. Howlader; M. S. Begum; M. C. Sheikh; R. Miyatake; E. Zangrando; H. Stoeckli-Evans

doi:10.1107/S2056989015000080

Crystal structure of S-hexyl (E)-3-(4-methylbenzylidene)dithiocarbazate

M. B.H. Howlader, M. S. Begum^*, M. C. Sheikh, R. Miyatake, E. Zangrando, H. Stoeckli-Evans

^*Corresponding author for this work

Center for Environmental Conservation and Research Safety

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

In the title compound, C₁₅H₂₂N₂S₂, the dithiocarbazate group adopts an E conformation with respect to the C=N bond of the benzylidene moiety. In the crystal, molecules are linked by pairs of N - H⋯S hydrogen bonds, forming inversion dimers with an R₂²(8) ring motif. The dimers are linked via C - H⋯π interactions, forming chains propagating along [100].

Original language	English
Pages (from-to)	o103-o104
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	71
Issue number	2
DOIs	https://doi.org/10.1107/S2056989015000080
State	Published - 2015/02/01

Keywords

Bidentate Schiff base
C - H⋯πinteractions
Crystal structure
N - H⋯S hydrogen bonds
S-hexyl dithiocarbazate

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "Crystal structure of S-hexyl (E)-3-(4-methylbenzylidene)dithiocarbazate",

abstract = "In the title compound, C15H22N2S2, the dithiocarbazate group adopts an E conformation with respect to the C=N bond of the benzylidene moiety. In the crystal, molecules are linked by pairs of N - H⋯S hydrogen bonds, forming inversion dimers with an R22(8) ring motif. The dimers are linked via C - H⋯π interactions, forming chains propagating along [100].",

keywords = "Bidentate Schiff base, C - H⋯πinteractions, Crystal structure, N - H⋯S hydrogen bonds, S-hexyl dithiocarbazate",

author = "Howlader, {M. B.H.} and Begum, {M. S.} and Sheikh, {M. C.} and R. Miyatake and E. Zangrando and H. Stoeckli-Evans",

year = "2015",

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doi = "10.1107/S2056989015000080",

language = "英語",

volume = "71",

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journal = "Acta Crystallographica Section E: Structure Reports Online",

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publisher = "International Union of Crystallography",

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T1 - Crystal structure of S-hexyl (E)-3-(4-methylbenzylidene)dithiocarbazate

AU - Howlader, M. B.H.

AU - Begum, M. S.

AU - Sheikh, M. C.

AU - Miyatake, R.

AU - Zangrando, E.

AU - Stoeckli-Evans, H.

PY - 2015/2/1

Y1 - 2015/2/1

N2 - In the title compound, C15H22N2S2, the dithiocarbazate group adopts an E conformation with respect to the C=N bond of the benzylidene moiety. In the crystal, molecules are linked by pairs of N - H⋯S hydrogen bonds, forming inversion dimers with an R22(8) ring motif. The dimers are linked via C - H⋯π interactions, forming chains propagating along [100].

AB - In the title compound, C15H22N2S2, the dithiocarbazate group adopts an E conformation with respect to the C=N bond of the benzylidene moiety. In the crystal, molecules are linked by pairs of N - H⋯S hydrogen bonds, forming inversion dimers with an R22(8) ring motif. The dimers are linked via C - H⋯π interactions, forming chains propagating along [100].

KW - Bidentate Schiff base

KW - C - H⋯πinteractions

KW - Crystal structure

KW - N - H⋯S hydrogen bonds

KW - S-hexyl dithiocarbazate

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DO - 10.1107/S2056989015000080

M3 - 学術論文

C2 - 25878852

AN - SCOPUS:84928110853

SN - 1600-5368

VL - 71

SP - o103-o104

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 2

ER -

Crystal structure of S-hexyl (E)-3-(4-methylbenzylidene)dithiocarbazate

Abstract

Keywords

ASJC Scopus subject areas

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