Crystal structure of bis[S-hexyl 3-(4-methylbenzylidene)dithiocarbazato-κ2N3,S]nickel(II)

M. B.H. Howlader; M. S. Begum; M. C. Sheikh; R. Miyatake; E. Zangrando; P. Dastidar

doi:10.1107/S2056989015000328

Crystal structure of bis[S-hexyl 3-(4-methylbenzylidene)dithiocarbazato-κ²N³,S]nickel(II)

M. B.H. Howlader, M. S. Begum^*, M. C. Sheikh, R. Miyatake, E. Zangrando, P. Dastidar

^*Corresponding author for this work

Center for Environmental Conservation and Research Safety

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

In the title complex, [Ni(C₁₅H₂₁N₂S₂)₂], the Ni^II atom exhibits a square-planar coordination geometry and is located on an inversion centre leading to a trans configuration of the N,S-chelating ligands. In the crystal, the complex molecules stack at a distance of 4.6738 (3) Å along the a axis, which exclude any significant interactions between the aromatic rings.

Original language	English
Pages (from-to)	m26-m27
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	71
Issue number	2
DOIs	https://doi.org/10.1107/S2056989015000328
State	Published - 2015/02/01

Keywords

Crystal structure
Dithiocarbazate
Nickel complex

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

Access to Document

10.1107/S2056989015000328

Cite this

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title = "Crystal structure of bis[S-hexyl 3-(4-methylbenzylidene)dithiocarbazato-κ2N3,S]nickel(II)",

abstract = "In the title complex, [Ni(C15H21N2S2)2], the NiII atom exhibits a square-planar coordination geometry and is located on an inversion centre leading to a trans configuration of the N,S-chelating ligands. In the crystal, the complex molecules stack at a distance of 4.6738 (3) {\AA} along the a axis, which exclude any significant interactions between the aromatic rings.",

keywords = "Crystal structure, Dithiocarbazate, Nickel complex",

author = "Howlader, {M. B.H.} and Begum, {M. S.} and Sheikh, {M. C.} and R. Miyatake and E. Zangrando and P. Dastidar",

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T1 - Crystal structure of bis[S-hexyl 3-(4-methylbenzylidene)dithiocarbazato-κ2N3,S]nickel(II)

AU - Howlader, M. B.H.

AU - Begum, M. S.

AU - Sheikh, M. C.

AU - Miyatake, R.

AU - Zangrando, E.

AU - Dastidar, P.

PY - 2015/2/1

Y1 - 2015/2/1

N2 - In the title complex, [Ni(C15H21N2S2)2], the NiII atom exhibits a square-planar coordination geometry and is located on an inversion centre leading to a trans configuration of the N,S-chelating ligands. In the crystal, the complex molecules stack at a distance of 4.6738 (3) Å along the a axis, which exclude any significant interactions between the aromatic rings.

AB - In the title complex, [Ni(C15H21N2S2)2], the NiII atom exhibits a square-planar coordination geometry and is located on an inversion centre leading to a trans configuration of the N,S-chelating ligands. In the crystal, the complex molecules stack at a distance of 4.6738 (3) Å along the a axis, which exclude any significant interactions between the aromatic rings.

KW - Crystal structure

KW - Dithiocarbazate

KW - Nickel complex

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DO - 10.1107/S2056989015000328

M3 - 学術論文

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JO - Acta Crystallographica Section E: Structure Reports Online

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