Crystal structure of bis[4-(allyloxy)-N0-(but-2-en-1ylidene)benzohydrazidato]nickel(II)

Sultana Shakila Khan; Md Belayet Hossain Howlader; Md Chanmiya Sheikh; Ryuta Miyatake; Ennio Zangrando

doi:10.1107/S2056989023002918

Crystal structure of bis[4-(allyloxy)-N⁰-(but-2-en-1ylidene)benzohydrazidato]nickel(II)

Sultana Shakila Khan, Md Belayet Hossain Howlader^*, Md Chanmiya Sheikh, Ryuta Miyatake, Ennio Zangrando

^*Corresponding author for this work

Center for Environmental Conservation and Research Safety

Research output: Contribution to journal › Article › peer-review

Abstract

In the title complex, [Ni(C₁₄H₁₅N₂O₂)₂], the nickel(II) atom exhibits a square-planar coordination geometry, being coordinated by two negatively charged N,O chelating ligands in a trans configuration, with the metal located on a crystallographic center of symmetry. The X-ray structural characterization showed the complex to be disordered over two orientations with refined occupancies of 0.898 (2) and 0.102 (2). The whole molecule is close to planar, the five- and six-membered rings subtending a dihedral angle of 7.5 (2)^◦. The crystal packing is supported by C—H‧ ‧ ‧π and C—H‧ ‧ ‧O interactions that form a di-periodic layered network.

Original language	English
Pages (from-to)	465-468
Number of pages	4
Journal	Acta Crystallographica Section E: Crystallographic Communications
Volume	79
Issue number	Pt 5
DOIs	https://doi.org/10.1107/S2056989023002918
State	Published - 2023/04/14

Keywords

allyloxy
benzohydrazide
crystal structure
nickel complex

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

Access to Document

10.1107/S2056989023002918

Cite this

@article{e5955e6b2420423198f93d77f91c7291,

title = "Crystal structure of bis[4-(allyloxy)-N0-(but-2-en-1ylidene)benzohydrazidato]nickel(II)",

abstract = "In the title complex, [Ni(C14H15N2O2)2], the nickel(II) atom exhibits a square-planar coordination geometry, being coordinated by two negatively charged N,O chelating ligands in a trans configuration, with the metal located on a crystallographic center of symmetry. The X-ray structural characterization showed the complex to be disordered over two orientations with refined occupancies of 0.898 (2) and 0.102 (2). The whole molecule is close to planar, the five- and six-membered rings subtending a dihedral angle of 7.5 (2)◦. The crystal packing is supported by C—H‧ ‧ ‧π and C—H‧ ‧ ‧O interactions that form a di-periodic layered network.",

keywords = "allyloxy, benzohydrazide, crystal structure, nickel complex",

author = "Khan, {Sultana Shakila} and Howlader, {Md Belayet Hossain} and Sheikh, {Md Chanmiya} and Ryuta Miyatake and Ennio Zangrando",

year = "2023",

month = apr,

day = "14",

doi = "10.1107/S2056989023002918",

language = "英語",

volume = "79",

pages = "465--468",

journal = "Acta Crystallographica Section E: Crystallographic Communications",

issn = "2056-9890",

publisher = "International Union of Crystallography",

number = "Pt 5",

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TY - JOUR

T1 - Crystal structure of bis[4-(allyloxy)-N0-(but-2-en-1ylidene)benzohydrazidato]nickel(II)

AU - Khan, Sultana Shakila

AU - Howlader, Md Belayet Hossain

AU - Sheikh, Md Chanmiya

AU - Miyatake, Ryuta

AU - Zangrando, Ennio

PY - 2023/4/14

Y1 - 2023/4/14

N2 - In the title complex, [Ni(C14H15N2O2)2], the nickel(II) atom exhibits a square-planar coordination geometry, being coordinated by two negatively charged N,O chelating ligands in a trans configuration, with the metal located on a crystallographic center of symmetry. The X-ray structural characterization showed the complex to be disordered over two orientations with refined occupancies of 0.898 (2) and 0.102 (2). The whole molecule is close to planar, the five- and six-membered rings subtending a dihedral angle of 7.5 (2)◦. The crystal packing is supported by C—H‧ ‧ ‧π and C—H‧ ‧ ‧O interactions that form a di-periodic layered network.

AB - In the title complex, [Ni(C14H15N2O2)2], the nickel(II) atom exhibits a square-planar coordination geometry, being coordinated by two negatively charged N,O chelating ligands in a trans configuration, with the metal located on a crystallographic center of symmetry. The X-ray structural characterization showed the complex to be disordered over two orientations with refined occupancies of 0.898 (2) and 0.102 (2). The whole molecule is close to planar, the five- and six-membered rings subtending a dihedral angle of 7.5 (2)◦. The crystal packing is supported by C—H‧ ‧ ‧π and C—H‧ ‧ ‧O interactions that form a di-periodic layered network.

KW - allyloxy

KW - benzohydrazide

KW - crystal structure

KW - nickel complex

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U2 - 10.1107/S2056989023002918

DO - 10.1107/S2056989023002918

M3 - 学術論文

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SP - 465

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JO - Acta Crystallographica Section E: Crystallographic Communications

JF - Acta Crystallographica Section E: Crystallographic Communications

IS - Pt 5

ER -