Crystal structure of 1,2-bis((benzylsulfanyl){2-[1-(2-hydroxyphenyl)ethylidene]hydrazin-1-ylidene}methyl)disulfane

M. A.A.A.A. Islam; M. C. Sheikh; M. H. Islam; R. Miyatake; E. Zangrando

doi:10.1107/S2056989016002371

Crystal structure of 1,2-bis((benzylsulfanyl){2-[1-(2-hydroxyphenyl)ethylidene]hydrazin-1-ylidene}methyl)disulfane

M. A.A.A.A. Islam, M. C. Sheikh^*, M. H. Islam, R. Miyatake, E. Zangrando

^*Corresponding author for this work

Center for Environmental Conservation and Research Safety

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

The title compound, C₃₂H₃₀N₄O₂S₄, consists of two Schiff base moieties, namely two S-benzyl-β-N-(2-hydroxyphenylethylidene)dithiocarbazate groups, which are connected through an S-S single bond. These two moieties are twisted with respect to each other, with a dihedral angle of 87.88(4)° between the S₂C=N planes. A bifurcated intramolecular O-H⋯(N,S) hydrogen bond is observed in each moiety. In the crystal, molecules are linked by pairs of C-H⋯O hydrogen bonds into inversion dimers. The dimers are further stacked in a column along the b axis through weak C-H⋯π interactions.

Original language	English
Pages (from-to)	337-339
Number of pages	3
Journal	Acta Crystallographica Section E: Crystallographic Communications
Volume	72
DOIs	https://doi.org/10.1107/S2056989016002371
State	Published - 2016

Keywords

Schiff base
crystal structure
dithiocarbazate
hydrogen bonds
hydroxyphenylethylidene

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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10.1107/S2056989016002371

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@article{73511d6cf6104ab3855a5ccdee1d404c,

title = "Crystal structure of 1,2-bis((benzylsulfanyl){2-[1-(2-hydroxyphenyl)ethylidene]hydrazin-1-ylidene}methyl)disulfane",

abstract = "The title compound, C32H30N4O2S4, consists of two Schiff base moieties, namely two S-benzyl-β-N-(2-hydroxyphenylethylidene)dithiocarbazate groups, which are connected through an S-S single bond. These two moieties are twisted with respect to each other, with a dihedral angle of 87.88(4)° between the S2C=N planes. A bifurcated intramolecular O-H⋯(N,S) hydrogen bond is observed in each moiety. In the crystal, molecules are linked by pairs of C-H⋯O hydrogen bonds into inversion dimers. The dimers are further stacked in a column along the b axis through weak C-H⋯π interactions.",

keywords = "Schiff base, crystal structure, dithiocarbazate, hydrogen bonds, hydroxyphenylethylidene",

author = "Islam, {M. A.A.A.A.} and Sheikh, {M. C.} and Islam, {M. H.} and R. Miyatake and E. Zangrando",

note = "Publisher Copyright: {\textcopyright} 2016 Islam et al.",

year = "2016",

doi = "10.1107/S2056989016002371",

language = "英語",

volume = "72",

pages = "337--339",

journal = "Acta Crystallographica Section E: Crystallographic Communications",

issn = "2056-9890",

publisher = "International Union of Crystallography",

}

TY - JOUR

T1 - Crystal structure of 1,2-bis((benzylsulfanyl){2-[1-(2-hydroxyphenyl)ethylidene]hydrazin-1-ylidene}methyl)disulfane

AU - Islam, M. A.A.A.A.

AU - Sheikh, M. C.

AU - Islam, M. H.

AU - Miyatake, R.

AU - Zangrando, E.

PY - 2016

Y1 - 2016

N2 - The title compound, C32H30N4O2S4, consists of two Schiff base moieties, namely two S-benzyl-β-N-(2-hydroxyphenylethylidene)dithiocarbazate groups, which are connected through an S-S single bond. These two moieties are twisted with respect to each other, with a dihedral angle of 87.88(4)° between the S2C=N planes. A bifurcated intramolecular O-H⋯(N,S) hydrogen bond is observed in each moiety. In the crystal, molecules are linked by pairs of C-H⋯O hydrogen bonds into inversion dimers. The dimers are further stacked in a column along the b axis through weak C-H⋯π interactions.

AB - The title compound, C32H30N4O2S4, consists of two Schiff base moieties, namely two S-benzyl-β-N-(2-hydroxyphenylethylidene)dithiocarbazate groups, which are connected through an S-S single bond. These two moieties are twisted with respect to each other, with a dihedral angle of 87.88(4)° between the S2C=N planes. A bifurcated intramolecular O-H⋯(N,S) hydrogen bond is observed in each moiety. In the crystal, molecules are linked by pairs of C-H⋯O hydrogen bonds into inversion dimers. The dimers are further stacked in a column along the b axis through weak C-H⋯π interactions.

KW - Schiff base

KW - crystal structure

KW - dithiocarbazate

KW - hydrogen bonds

KW - hydroxyphenylethylidene

UR - http://www.scopus.com/inward/record.url?scp=84960075325&partnerID=8YFLogxK

U2 - 10.1107/S2056989016002371

DO - 10.1107/S2056989016002371

M3 - 学術論文

AN - SCOPUS:84960075325

SN - 2056-9890

VL - 72

SP - 337

EP - 339

JO - Acta Crystallographica Section E: Crystallographic Communications

JF - Acta Crystallographica Section E: Crystallographic Communications

ER -

Crystal structure of 1,2-bis((benzylsulfanyl){2-[1-(2-hydroxyphenyl)ethylidene]hydrazin-1-ylidene}methyl)disulfane

Abstract

Keywords

ASJC Scopus subject areas

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