Copper-iron supported bimodal pore catalyst and its application for higher alcohols synthesis

Mingyue Ding; Junling Tu; Jianguo Liu; Noritatsu Tsubaki; Tiejun Wang; Longlong Ma

doi:10.1016/j.cattod.2014.01.039

Copper-iron supported bimodal pore catalyst and its application for higher alcohols synthesis

Mingyue Ding, Junling Tu, Jianguo Liu, Noritatsu Tsubaki, Tiejun Wang^*, Longlong Ma

^*Corresponding author for this work

Applied Chemistry

Research output: Contribution to journal › Article › peer-review

30 Scopus citations

Abstract

A Cu-Fe supported bimodal pore catalyst prepared by incipient-wetness impregnation exhibited two kinds of nano-pores. Increasing amount of copper and iron species decreased BET surface area and the size of both the small pores and large pores, while promoted the aggregation of bi-metal particles inside the large pores. Higher bimetal species content in the bimodal derived catalyst facilitated the reduction of metal oxides and the formation of metallic Cu and iron carbides during higher alcohols synthesis (HAS) reaction. The increasing of active bimetal sites and spatial effect of pore structures enhanced probably the synergistic effect of Cu-Fe, promoting the catalytic activity for HAS. Furthermore, the bimodal derived catalyst with higher Cu and Fe species loading resulted in a larger metallic particle size and lower surface area, which facilitated the product distribution of alcohols shifting towards C ₂⁺OH.

Original language	English
Pages (from-to)	278-284
Number of pages	7
Journal	Catalysis Today
Volume	234
DOIs	https://doi.org/10.1016/j.cattod.2014.01.039
State	Published - 2014/10/01

Keywords

Bimodal pore support
Copper and iron species
Higher alcohols synthesis
Synergistic effect

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1016/j.cattod.2014.01.039

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title = "Copper-iron supported bimodal pore catalyst and its application for higher alcohols synthesis",

abstract = "A Cu-Fe supported bimodal pore catalyst prepared by incipient-wetness impregnation exhibited two kinds of nano-pores. Increasing amount of copper and iron species decreased BET surface area and the size of both the small pores and large pores, while promoted the aggregation of bi-metal particles inside the large pores. Higher bimetal species content in the bimodal derived catalyst facilitated the reduction of metal oxides and the formation of metallic Cu and iron carbides during higher alcohols synthesis (HAS) reaction. The increasing of active bimetal sites and spatial effect of pore structures enhanced probably the synergistic effect of Cu-Fe, promoting the catalytic activity for HAS. Furthermore, the bimodal derived catalyst with higher Cu and Fe species loading resulted in a larger metallic particle size and lower surface area, which facilitated the product distribution of alcohols shifting towards C 2+OH.",

keywords = "Bimodal pore support, Copper and iron species, Higher alcohols synthesis, Synergistic effect",

author = "Mingyue Ding and Junling Tu and Jianguo Liu and Noritatsu Tsubaki and Tiejun Wang and Longlong Ma",

note = "Funding Information: The authors gratefully acknowledge the financial support from the Natural Science Foundation of China ( 51206172 , U1362109 ), National Key Scientific Instrument and Equipment development Project ( 2012YQ16000704 ) and National Key Basic Research Program of China (No. 2013CB228105 ).",

year = "2014",

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doi = "10.1016/j.cattod.2014.01.039",

language = "英語",

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pages = "278--284",

journal = "Catalysis Today",

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T1 - Copper-iron supported bimodal pore catalyst and its application for higher alcohols synthesis

AU - Ding, Mingyue

AU - Tu, Junling

AU - Liu, Jianguo

AU - Tsubaki, Noritatsu

AU - Wang, Tiejun

AU - Ma, Longlong

N1 - Funding Information: The authors gratefully acknowledge the financial support from the Natural Science Foundation of China ( 51206172 , U1362109 ), National Key Scientific Instrument and Equipment development Project ( 2012YQ16000704 ) and National Key Basic Research Program of China (No. 2013CB228105 ).

PY - 2014/10/1

Y1 - 2014/10/1

N2 - A Cu-Fe supported bimodal pore catalyst prepared by incipient-wetness impregnation exhibited two kinds of nano-pores. Increasing amount of copper and iron species decreased BET surface area and the size of both the small pores and large pores, while promoted the aggregation of bi-metal particles inside the large pores. Higher bimetal species content in the bimodal derived catalyst facilitated the reduction of metal oxides and the formation of metallic Cu and iron carbides during higher alcohols synthesis (HAS) reaction. The increasing of active bimetal sites and spatial effect of pore structures enhanced probably the synergistic effect of Cu-Fe, promoting the catalytic activity for HAS. Furthermore, the bimodal derived catalyst with higher Cu and Fe species loading resulted in a larger metallic particle size and lower surface area, which facilitated the product distribution of alcohols shifting towards C 2+OH.

AB - A Cu-Fe supported bimodal pore catalyst prepared by incipient-wetness impregnation exhibited two kinds of nano-pores. Increasing amount of copper and iron species decreased BET surface area and the size of both the small pores and large pores, while promoted the aggregation of bi-metal particles inside the large pores. Higher bimetal species content in the bimodal derived catalyst facilitated the reduction of metal oxides and the formation of metallic Cu and iron carbides during higher alcohols synthesis (HAS) reaction. The increasing of active bimetal sites and spatial effect of pore structures enhanced probably the synergistic effect of Cu-Fe, promoting the catalytic activity for HAS. Furthermore, the bimodal derived catalyst with higher Cu and Fe species loading resulted in a larger metallic particle size and lower surface area, which facilitated the product distribution of alcohols shifting towards C 2+OH.

KW - Bimodal pore support

KW - Copper and iron species

KW - Higher alcohols synthesis

KW - Synergistic effect

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U2 - 10.1016/j.cattod.2014.01.039

DO - 10.1016/j.cattod.2014.01.039

M3 - 学術論文

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SN - 0920-5861

VL - 234

SP - 278

EP - 284

JO - Catalysis Today

JF - Catalysis Today

ER -

Copper-iron supported bimodal pore catalyst and its application for higher alcohols synthesis

Abstract

Keywords

ASJC Scopus subject areas

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