Control of Emissive Excited States of Silver(I) Halogenido Coordination Polymers by a Solid Solution Approach

Masaaki Dosen; Yoshitaka Kawada; Seiko Shibata; Kiyoshi Tsuge; Yoichi Sasaki; Atsushi Kobayashi; Masako Kato; Shoji Ishizaka; Noboru Kitamura

doi:10.1021/acs.inorgchem.9b00538

Control of Emissive Excited States of Silver(I) Halogenido Coordination Polymers by a Solid Solution Approach

Masaaki Dosen, Yoshitaka Kawada, Seiko Shibata, Kiyoshi Tsuge^*, Yoichi Sasaki, Atsushi Kobayashi, Masako Kato, Shoji Ishizaka, Noboru Kitamura

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

Luminescent silver(I) halogenido coordination polymers [Ag₂X₂(PPh₃)₂(bpy)]_n (X = I, Br, Cl) have been prepared. The iodido and bromido complexes exhibit strong blue phosphorescence assignable to the ³Ï€-Ï€*-excited-state of bpy, whereas the chlorido complex shows luminescence thermochromism due to the Ï€-Ï€*-state of bpy and charge transfer from the {Ag₂Cl₂} core to the bpy Ï€*-orbital. Taking advantage of their structural similarities, we prepared a series of mixed-halogenido silver(I) complexes [Ag₂(X_xX′_(1-x))₂(PPh₃)₂(bpy)]_n (X, X′ = I, Br, Cl) at varying molar fractions as solid solutions. The mixed-halogenido complexes are as strongly luminescent as their parent complexes. The detailed study of their structure and emissive properties revealed smooth energy migration between the luminescent units and modification of the luminescence properties based on the planarity of bpy.

Original language	English
Pages (from-to)	8419-8431
Number of pages	13
Journal	Inorganic Chemistry
Volume	58
Issue number	13
DOIs	https://doi.org/10.1021/acs.inorgchem.9b00538
State	Published - 2019/07/01

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

Access to Document

10.1021/acs.inorgchem.9b00538

Cite this

@article{9957264925dd4daeae1f1cbb40015399,

title = "Control of Emissive Excited States of Silver(I) Halogenido Coordination Polymers by a Solid Solution Approach",

abstract = "Luminescent silver(I) halogenido coordination polymers [Ag2X2(PPh3)2(bpy)]n (X = I, Br, Cl) have been prepared. The iodido and bromido complexes exhibit strong blue phosphorescence assignable to the 3{\"I}€-{\"I}€*-excited-state of bpy, whereas the chlorido complex shows luminescence thermochromism due to the {\"I}€-{\"I}€*-state of bpy and charge transfer from the {Ag2Cl2} core to the bpy {\"I}€*-orbital. Taking advantage of their structural similarities, we prepared a series of mixed-halogenido silver(I) complexes [Ag2(XxX′(1-x))2(PPh3)2(bpy)]n (X, X′ = I, Br, Cl) at varying molar fractions as solid solutions. The mixed-halogenido complexes are as strongly luminescent as their parent complexes. The detailed study of their structure and emissive properties revealed smooth energy migration between the luminescent units and modification of the luminescence properties based on the planarity of bpy.",

author = "Masaaki Dosen and Yoshitaka Kawada and Seiko Shibata and Kiyoshi Tsuge and Yoichi Sasaki and Atsushi Kobayashi and Masako Kato and Shoji Ishizaka and Noboru Kitamura",

note = "Publisher Copyright: {\textcopyright} 2019 American Chemical Society.",

year = "2019",

month = jul,

day = "1",

doi = "10.1021/acs.inorgchem.9b00538",

language = "英語",

volume = "58",

pages = "8419--8431",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "13",

}

TY - JOUR

T1 - Control of Emissive Excited States of Silver(I) Halogenido Coordination Polymers by a Solid Solution Approach

AU - Dosen, Masaaki

AU - Kawada, Yoshitaka

AU - Shibata, Seiko

AU - Tsuge, Kiyoshi

AU - Sasaki, Yoichi

AU - Kobayashi, Atsushi

AU - Kato, Masako

AU - Ishizaka, Shoji

AU - Kitamura, Noboru

PY - 2019/7/1

Y1 - 2019/7/1

N2 - Luminescent silver(I) halogenido coordination polymers [Ag2X2(PPh3)2(bpy)]n (X = I, Br, Cl) have been prepared. The iodido and bromido complexes exhibit strong blue phosphorescence assignable to the 3Ï€-Ï€*-excited-state of bpy, whereas the chlorido complex shows luminescence thermochromism due to the Ï€-Ï€*-state of bpy and charge transfer from the {Ag2Cl2} core to the bpy Ï€*-orbital. Taking advantage of their structural similarities, we prepared a series of mixed-halogenido silver(I) complexes [Ag2(XxX′(1-x))2(PPh3)2(bpy)]n (X, X′ = I, Br, Cl) at varying molar fractions as solid solutions. The mixed-halogenido complexes are as strongly luminescent as their parent complexes. The detailed study of their structure and emissive properties revealed smooth energy migration between the luminescent units and modification of the luminescence properties based on the planarity of bpy.

AB - Luminescent silver(I) halogenido coordination polymers [Ag2X2(PPh3)2(bpy)]n (X = I, Br, Cl) have been prepared. The iodido and bromido complexes exhibit strong blue phosphorescence assignable to the 3Ï€-Ï€*-excited-state of bpy, whereas the chlorido complex shows luminescence thermochromism due to the Ï€-Ï€*-state of bpy and charge transfer from the {Ag2Cl2} core to the bpy Ï€*-orbital. Taking advantage of their structural similarities, we prepared a series of mixed-halogenido silver(I) complexes [Ag2(XxX′(1-x))2(PPh3)2(bpy)]n (X, X′ = I, Br, Cl) at varying molar fractions as solid solutions. The mixed-halogenido complexes are as strongly luminescent as their parent complexes. The detailed study of their structure and emissive properties revealed smooth energy migration between the luminescent units and modification of the luminescence properties based on the planarity of bpy.

UR - http://www.scopus.com/inward/record.url?scp=85067463042&partnerID=8YFLogxK

U2 - 10.1021/acs.inorgchem.9b00538

DO - 10.1021/acs.inorgchem.9b00538

M3 - 学術論文

C2 - 31179696

AN - SCOPUS:85067463042

SN - 0020-1669

VL - 58

SP - 8419

EP - 8431

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 13

ER -

Control of Emissive Excited States of Silver(I) Halogenido Coordination Polymers by a Solid Solution Approach

Abstract

ASJC Scopus subject areas

Access to Document

Fingerprint

Cite this