Construction of cis-fused hydrindane skeleton with a lactone tether utilizing intramolecular diels-Alder reaction

Shuqiang Yin, Kenji Takai, Daishiro Minato, Kenji Sugimoto, Hideki Ohtsu, Kiyoshi Tsuge, Yuji Matsuya

Research output: Contribution to journalArticlepeer-review

2 Scopus citations

Abstract

Synthetically important, cis-fused hydrindane skeleton having quaternary angular stereogenic centers was selectively furnished by intramolecular Diels-Alder reaction of ester-Tethered precursor via endo transition state. The reaction was applicable for a construction of the steroidal BCD ring system with cis-hydrindane framework.

Original languageEnglish
Pages (from-to)783-791
Number of pages9
JournalHeterocycles
Volume93
Issue number2
DOIs
StatePublished - 2016

ASJC Scopus subject areas

  • Analytical Chemistry
  • Pharmacology
  • Organic Chemistry

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