Construction of cis-fused hydrindane skeleton with a lactone tether utilizing intramolecular diels-Alder reaction

Shuqiang Yin; Kenji Takai; Daishiro Minato; Kenji Sugimoto; Hideki Ohtsu; Kiyoshi Tsuge; Yuji Matsuya

doi:10.3987/COM-15-S(T)34

Construction of cis-fused hydrindane skeleton with a lactone tether utilizing intramolecular diels-Alder reaction

Shuqiang Yin, Kenji Takai, Daishiro Minato, Kenji Sugimoto, Hideki Ohtsu, Kiyoshi Tsuge, Yuji Matsuya

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Synthetically important, cis-fused hydrindane skeleton having quaternary angular stereogenic centers was selectively furnished by intramolecular Diels-Alder reaction of ester-Tethered precursor via endo transition state. The reaction was applicable for a construction of the steroidal BCD ring system with cis-hydrindane framework.

Original language	English
Pages (from-to)	783-791
Number of pages	9
Journal	Heterocycles
Volume	93
Issue number	2
DOIs	https://doi.org/10.3987/COM-15-S(T)34
State	Published - 2016

ASJC Scopus subject areas

Analytical Chemistry
Pharmacology
Organic Chemistry

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10.3987/COM-15-S(T)34

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title = "Construction of cis-fused hydrindane skeleton with a lactone tether utilizing intramolecular diels-Alder reaction",

abstract = "Synthetically important, cis-fused hydrindane skeleton having quaternary angular stereogenic centers was selectively furnished by intramolecular Diels-Alder reaction of ester-Tethered precursor via endo transition state. The reaction was applicable for a construction of the steroidal BCD ring system with cis-hydrindane framework.",

author = "Shuqiang Yin and Kenji Takai and Daishiro Minato and Kenji Sugimoto and Hideki Ohtsu and Kiyoshi Tsuge and Yuji Matsuya",

note = "Publisher Copyright: {\textcopyright} 2016 The Japan Institute of Heterocyclic Chemistry.",

year = "2016",

doi = "10.3987/COM-15-S(T)34",

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AU - Yin, Shuqiang

AU - Takai, Kenji

AU - Minato, Daishiro

AU - Sugimoto, Kenji

AU - Ohtsu, Hideki

AU - Tsuge, Kiyoshi

AU - Matsuya, Yuji

PY - 2016

Y1 - 2016

N2 - Synthetically important, cis-fused hydrindane skeleton having quaternary angular stereogenic centers was selectively furnished by intramolecular Diels-Alder reaction of ester-Tethered precursor via endo transition state. The reaction was applicable for a construction of the steroidal BCD ring system with cis-hydrindane framework.

AB - Synthetically important, cis-fused hydrindane skeleton having quaternary angular stereogenic centers was selectively furnished by intramolecular Diels-Alder reaction of ester-Tethered precursor via endo transition state. The reaction was applicable for a construction of the steroidal BCD ring system with cis-hydrindane framework.

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DO - 10.3987/COM-15-S(T)34

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SN - 0385-5414

VL - 93

SP - 783

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JO - Heterocycles

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ER -

Construction of cis-fused hydrindane skeleton with a lactone tether utilizing intramolecular diels-Alder reaction

Abstract

ASJC Scopus subject areas

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