Concise total synthesis of (-)-mersicarpine

Yusuke Iwama; Kentaro Okano; Kenji Sugimoto; Hidetoshi Tokuyama

doi:10.1021/ol300735g

Concise total synthesis of (-)-mersicarpine

Yusuke Iwama, Kentaro Okano, Kenji Sugimoto, Hidetoshi Tokuyama^*

^*Corresponding author for this work

Synthetic and Medicinal Chemistry

Research output: Contribution to journal › Article › peer-review

50 Citations (SciVal)

Abstract

A concise total synthesis of (-)-mersicarpine from a known cyclohexanone was accomplished. The azepinoindole core was constructed by a DIBAL-H-mediated reductive ring-expansion reaction of oxime.

Original language	English
Pages (from-to)	2320-2322
Number of pages	3
Journal	Organic Letters
Volume	14
Issue number	9
DOIs	https://doi.org/10.1021/ol300735g
State	Published - 2012/05/04

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol300735g

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title = "Concise total synthesis of (-)-mersicarpine",

abstract = "A concise total synthesis of (-)-mersicarpine from a known cyclohexanone was accomplished. The azepinoindole core was constructed by a DIBAL-H-mediated reductive ring-expansion reaction of oxime.",

author = "Yusuke Iwama and Kentaro Okano and Kenji Sugimoto and Hidetoshi Tokuyama",

year = "2012",

month = may,

day = "4",

doi = "10.1021/ol300735g",

language = "英語",

volume = "14",

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journal = "Organic Letters",

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T1 - Concise total synthesis of (-)-mersicarpine

AU - Iwama, Yusuke

AU - Okano, Kentaro

AU - Sugimoto, Kenji

AU - Tokuyama, Hidetoshi

PY - 2012/5/4

Y1 - 2012/5/4

N2 - A concise total synthesis of (-)-mersicarpine from a known cyclohexanone was accomplished. The azepinoindole core was constructed by a DIBAL-H-mediated reductive ring-expansion reaction of oxime.

AB - A concise total synthesis of (-)-mersicarpine from a known cyclohexanone was accomplished. The azepinoindole core was constructed by a DIBAL-H-mediated reductive ring-expansion reaction of oxime.

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U2 - 10.1021/ol300735g

DO - 10.1021/ol300735g

M3 - 学術論文

C2 - 22512929

AN - SCOPUS:84860632643

SN - 1523-7060

VL - 14

SP - 2320

EP - 2322

JO - Organic Letters

JF - Organic Letters

IS - 9

ER -

Concise total synthesis of (-)-mersicarpine

Abstract

ASJC Scopus subject areas

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