Catalytic oligomerization of isobutyl alcohol to jet fuels over dealuminated zeolite Beta

Xiaoyu Guo; Lisheng Guo; Yan Zeng; Rungtiwa Kosol; Xinhua Gao; Yoshiharu Yoneyama; Guohui Yang; Noritatsu Tsubaki

doi:10.1016/j.cattod.2020.04.047

Catalytic oligomerization of isobutyl alcohol to jet fuels over dealuminated zeolite Beta

Xiaoyu Guo, Lisheng Guo, Yan Zeng, Rungtiwa Kosol, Xinhua Gao, Yoshiharu Yoneyama, Guohui Yang^*, Noritatsu Tsubaki^*

^*Corresponding author for this work

Applied Chemistry

Research output: Contribution to journal › Article › peer-review

28 Scopus citations

Abstract

Various dealuminum methods of zeolite Beta to generate the jet fuels by converting isobutyl alcohol has been investigated in detail. And related factors of the zeolite catalyst such as acid site, pore structure, and pore size which can influence reactive activity, were also studied utilizing XRD, SEM, XRF, Nitrogen adsorption-desorption, NH₃-TPD, Py-FTIR, and ²⁷Al solid-state NMR. Removal of extra-framework aluminum or part of framework aluminum by hydrochloric acid dealumination, is able to improve the diffusion property of the products in the channel of zeolite Beta via increasing the ratio of Lewis/Brønsted. Consequently, isobutyl alcohol can be quantitatively oligomerized over dealuminated zeolite Beta with the selectivity of C₈₋₁₆ exceeding 50 % at a conversion of 98 %. Moreover, the deactivated catalyst can be easily regenerated by calcining it in flowing air. High conversion, high jet fuels selectivity, and facile regeneration make it an attractive potential catalyst for isobutyl alcohol oligomerization reaction.

Original language	English
Pages (from-to)	196-203
Number of pages	8
Journal	Catalysis Today
Volume	368
DOIs	https://doi.org/10.1016/j.cattod.2020.04.047
State	Published - 2021/05/15

Keywords

Beta zeolite
Dealumination
Isobutyl alcohol
Jet fuels
Oligomerization

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1016/j.cattod.2020.04.047

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@article{a1539eca004b4dfdada89106eef8307e,

title = "Catalytic oligomerization of isobutyl alcohol to jet fuels over dealuminated zeolite Beta",

abstract = "Various dealuminum methods of zeolite Beta to generate the jet fuels by converting isobutyl alcohol has been investigated in detail. And related factors of the zeolite catalyst such as acid site, pore structure, and pore size which can influence reactive activity, were also studied utilizing XRD, SEM, XRF, Nitrogen adsorption-desorption, NH3-TPD, Py-FTIR, and 27Al solid-state NMR. Removal of extra-framework aluminum or part of framework aluminum by hydrochloric acid dealumination, is able to improve the diffusion property of the products in the channel of zeolite Beta via increasing the ratio of Lewis/Br{\o}nsted. Consequently, isobutyl alcohol can be quantitatively oligomerized over dealuminated zeolite Beta with the selectivity of C8−16 exceeding 50 % at a conversion of 98 %. Moreover, the deactivated catalyst can be easily regenerated by calcining it in flowing air. High conversion, high jet fuels selectivity, and facile regeneration make it an attractive potential catalyst for isobutyl alcohol oligomerization reaction.",

keywords = "Beta zeolite, Dealumination, Isobutyl alcohol, Jet fuels, Oligomerization",

author = "Xiaoyu Guo and Lisheng Guo and Yan Zeng and Rungtiwa Kosol and Xinhua Gao and Yoshiharu Yoneyama and Guohui Yang and Noritatsu Tsubaki",

note = "Publisher Copyright: {\textcopyright} 2020 Elsevier B.V.",

year = "2021",

month = may,

day = "15",

doi = "10.1016/j.cattod.2020.04.047",

language = "英語",

volume = "368",

pages = "196--203",

journal = "Catalysis Today",

issn = "0920-5861",

publisher = "Elsevier B.V.",

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T1 - Catalytic oligomerization of isobutyl alcohol to jet fuels over dealuminated zeolite Beta

AU - Guo, Xiaoyu

AU - Guo, Lisheng

AU - Zeng, Yan

AU - Kosol, Rungtiwa

AU - Gao, Xinhua

AU - Yoneyama, Yoshiharu

AU - Yang, Guohui

AU - Tsubaki, Noritatsu

PY - 2021/5/15

Y1 - 2021/5/15

N2 - Various dealuminum methods of zeolite Beta to generate the jet fuels by converting isobutyl alcohol has been investigated in detail. And related factors of the zeolite catalyst such as acid site, pore structure, and pore size which can influence reactive activity, were also studied utilizing XRD, SEM, XRF, Nitrogen adsorption-desorption, NH3-TPD, Py-FTIR, and 27Al solid-state NMR. Removal of extra-framework aluminum or part of framework aluminum by hydrochloric acid dealumination, is able to improve the diffusion property of the products in the channel of zeolite Beta via increasing the ratio of Lewis/Brønsted. Consequently, isobutyl alcohol can be quantitatively oligomerized over dealuminated zeolite Beta with the selectivity of C8−16 exceeding 50 % at a conversion of 98 %. Moreover, the deactivated catalyst can be easily regenerated by calcining it in flowing air. High conversion, high jet fuels selectivity, and facile regeneration make it an attractive potential catalyst for isobutyl alcohol oligomerization reaction.

AB - Various dealuminum methods of zeolite Beta to generate the jet fuels by converting isobutyl alcohol has been investigated in detail. And related factors of the zeolite catalyst such as acid site, pore structure, and pore size which can influence reactive activity, were also studied utilizing XRD, SEM, XRF, Nitrogen adsorption-desorption, NH3-TPD, Py-FTIR, and 27Al solid-state NMR. Removal of extra-framework aluminum or part of framework aluminum by hydrochloric acid dealumination, is able to improve the diffusion property of the products in the channel of zeolite Beta via increasing the ratio of Lewis/Brønsted. Consequently, isobutyl alcohol can be quantitatively oligomerized over dealuminated zeolite Beta with the selectivity of C8−16 exceeding 50 % at a conversion of 98 %. Moreover, the deactivated catalyst can be easily regenerated by calcining it in flowing air. High conversion, high jet fuels selectivity, and facile regeneration make it an attractive potential catalyst for isobutyl alcohol oligomerization reaction.

KW - Beta zeolite

KW - Dealumination

KW - Isobutyl alcohol

KW - Jet fuels

KW - Oligomerization

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DO - 10.1016/j.cattod.2020.04.047

M3 - 学術論文

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VL - 368

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EP - 203

JO - Catalysis Today

JF - Catalysis Today

ER -

Catalytic oligomerization of isobutyl alcohol to jet fuels over dealuminated zeolite Beta

Abstract

Keywords

ASJC Scopus subject areas

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