Bis[S-octyl 3-(2-methylpropylidene)dithiocarbaz-ato-j2N3,S]nickel(II)

Sultana Shakila Khan; Md Belayet Hossain Howlader; Md Chanmiya Sheikh; Ryuta Miyatake; Ennio Zangrando

doi:10.1107/S241431462400186X

Bis[S-octyl 3-(2-methylpropylidene)dithiocarbaz-ato-j²N³,S]nickel(II)

Sultana Shakila Khan, Md Belayet Hossain Howlader^*, Md Chanmiya Sheikh, Ryuta Miyatake, Ennio Zangrando

^*Corresponding author for this work

Center for Environmental Conservation and Research Safety

Research output: Contribution to journal › Article › peer-review

Abstract

The central Ni^II atom in the title complex, [Ni(C₁₃H₂₅N₂S₂)₂], is located on an inversion center and adopts a roughly square-planar coordination environment defined by two chelating N,S donor sets of two symmetry-related ligands in a trans configuration. The Ni—N and Ni—S bond lenghts are 1.9193 (14) and 2.1788 (5) A , respectively, with a chelating N—Ni—S bond angle of 86.05 (4). These data are compared with those measured for similar dithiocarbazato ligands that bear n-octyl or n-hexyl alkyl chains. Slight differences are observed with respect to the phenylethylidene derivative where the ligands are bound cis relative to one another.

Original language	English
Article number	x240186
Journal	IUCrData
Volume	9
Issue number	Pt 3
DOIs	https://doi.org/10.1107/S241431462400186X
State	Published - 2024/03/01

Keywords

Ni complex
crystal structure
dithiocarbazato ligand
octyl alkyl chain
trans configuration complex

ASJC Scopus subject areas

Analytical Chemistry
Organic Chemistry
Inorganic Chemistry

Access to Document

10.1107/S241431462400186X

Cite this

@article{846937f0cb824ea9a56950be338a7f1b,

title = "Bis[S-octyl 3-(2-methylpropylidene)dithiocarbaz-ato-j2N3,S]nickel(II)",

abstract = "The central NiII atom in the title complex, [Ni(C13H25N2S2)2], is located on an inversion center and adopts a roughly square-planar coordination environment defined by two chelating N,S donor sets of two symmetry-related ligands in a trans configuration. The Ni—N and Ni—S bond lenghts are 1.9193 (14) and 2.1788 (5) A , respectively, with a chelating N—Ni—S bond angle of 86.05 (4). These data are compared with those measured for similar dithiocarbazato ligands that bear n-octyl or n-hexyl alkyl chains. Slight differences are observed with respect to the phenylethylidene derivative where the ligands are bound cis relative to one another.",

keywords = "Ni complex, crystal structure, dithiocarbazato ligand, octyl alkyl chain, trans configuration complex",

author = "Khan, {Sultana Shakila} and {Belayet Hossain Howlader}, Md and {Chanmiya Sheikh}, Md and Ryuta Miyatake and Ennio Zangrando",

year = "2024",

month = mar,

day = "1",

doi = "10.1107/S241431462400186X",

language = "英語",

volume = "9",

journal = "IUCrData",

issn = "2414-3146",

publisher = "International Union of Crystallography",

number = "Pt 3",

}

TY - JOUR

T1 - Bis[S-octyl 3-(2-methylpropylidene)dithiocarbaz-ato-j2N3,S]nickel(II)

AU - Khan, Sultana Shakila

AU - Belayet Hossain Howlader, Md

AU - Chanmiya Sheikh, Md

AU - Miyatake, Ryuta

AU - Zangrando, Ennio

PY - 2024/3/1

Y1 - 2024/3/1

N2 - The central NiII atom in the title complex, [Ni(C13H25N2S2)2], is located on an inversion center and adopts a roughly square-planar coordination environment defined by two chelating N,S donor sets of two symmetry-related ligands in a trans configuration. The Ni—N and Ni—S bond lenghts are 1.9193 (14) and 2.1788 (5) A , respectively, with a chelating N—Ni—S bond angle of 86.05 (4). These data are compared with those measured for similar dithiocarbazato ligands that bear n-octyl or n-hexyl alkyl chains. Slight differences are observed with respect to the phenylethylidene derivative where the ligands are bound cis relative to one another.

AB - The central NiII atom in the title complex, [Ni(C13H25N2S2)2], is located on an inversion center and adopts a roughly square-planar coordination environment defined by two chelating N,S donor sets of two symmetry-related ligands in a trans configuration. The Ni—N and Ni—S bond lenghts are 1.9193 (14) and 2.1788 (5) A , respectively, with a chelating N—Ni—S bond angle of 86.05 (4). These data are compared with those measured for similar dithiocarbazato ligands that bear n-octyl or n-hexyl alkyl chains. Slight differences are observed with respect to the phenylethylidene derivative where the ligands are bound cis relative to one another.

KW - Ni complex

KW - crystal structure

KW - dithiocarbazato ligand

KW - octyl alkyl chain

KW - trans configuration complex

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U2 - 10.1107/S241431462400186X

DO - 10.1107/S241431462400186X

M3 - 学術論文

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AN - SCOPUS:85189668896

SN - 2414-3146

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