Autoxidation of thiol-containing amino acid to its disulfide derivative that links two copper(II) centers: The important role of auxiliary ligand

Hiroyuki Seko; Kiyoshi Tsuge; Asako Igashira-Kamiyama; Tatsuya Kawamoto; Takumi Konno

doi:10.1039/b913989c

Autoxidation of thiol-containing amino acid to its disulfide derivative that links two copper(II) centers: The important role of auxiliary ligand

Hiroyuki Seko, Kiyoshi Tsuge, Asako Igashira-Kamiyama, Tatsuya Kawamoto, Takumi Konno^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

Treatment of Cu(AcO)₂ with D-penicillamine or L-cysteine in the presence of 2,2′-bipyridine afforded dicopper(II) complexes with a bis(bidentate-N,O) disulfide ligand, the formation mechanism of which was discussed on the basis of Cu^II-thiolate interaction affected by an auxiliary ligand.

Original language	English
Pages (from-to)	1962-1964
Number of pages	3
Journal	Chemical Communications
Volume	46
Issue number	11
DOIs	https://doi.org/10.1039/b913989c
State	Published - 2010

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/b913989c

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title = "Autoxidation of thiol-containing amino acid to its disulfide derivative that links two copper(II) centers: The important role of auxiliary ligand",

abstract = "Treatment of Cu(AcO)2 with D-penicillamine or L-cysteine in the presence of 2,2′-bipyridine afforded dicopper(II) complexes with a bis(bidentate-N,O) disulfide ligand, the formation mechanism of which was discussed on the basis of CuII-thiolate interaction affected by an auxiliary ligand.",

author = "Hiroyuki Seko and Kiyoshi Tsuge and Asako Igashira-Kamiyama and Tatsuya Kawamoto and Takumi Konno",

year = "2010",

doi = "10.1039/b913989c",

language = "英語",

volume = "46",

pages = "1962--1964",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T1 - Autoxidation of thiol-containing amino acid to its disulfide derivative that links two copper(II) centers

T2 - The important role of auxiliary ligand

AU - Seko, Hiroyuki

AU - Tsuge, Kiyoshi

AU - Igashira-Kamiyama, Asako

AU - Kawamoto, Tatsuya

AU - Konno, Takumi

PY - 2010

Y1 - 2010

N2 - Treatment of Cu(AcO)2 with D-penicillamine or L-cysteine in the presence of 2,2′-bipyridine afforded dicopper(II) complexes with a bis(bidentate-N,O) disulfide ligand, the formation mechanism of which was discussed on the basis of CuII-thiolate interaction affected by an auxiliary ligand.

AB - Treatment of Cu(AcO)2 with D-penicillamine or L-cysteine in the presence of 2,2′-bipyridine afforded dicopper(II) complexes with a bis(bidentate-N,O) disulfide ligand, the formation mechanism of which was discussed on the basis of CuII-thiolate interaction affected by an auxiliary ligand.

UR - http://www.scopus.com/inward/record.url?scp=77949393653&partnerID=8YFLogxK

U2 - 10.1039/b913989c

DO - 10.1039/b913989c

M3 - 学術論文

C2 - 20198267

AN - SCOPUS:77949393653

SN - 1359-7345

VL - 46

SP - 1962

EP - 1964

JO - Chemical Communications

JF - Chemical Communications

IS - 11

ER -

Autoxidation of thiol-containing amino acid to its disulfide derivative that links two copper(II) centers: The important role of auxiliary ligand

Abstract

ASJC Scopus subject areas

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