Autoionization of NO in an excited valence state affected by perturbations from valence-Rydberg mixing

Koichiro Mitsuke; Yasumasa Hikosaka; Takumi Hikida; Hideo Hattori

doi:10.1016/0368-2048(96)02880-0

Autoionization of NO in an excited valence state affected by perturbations from valence-Rydberg mixing

Koichiro Mitsuke^*, Yasumasa Hikosaka, Takumi Hikida, Hideo Hattori

^*Corresponding author for this work

Faculty of Liberal Arts and Sciences

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

A two-dimensional photoelectron spectrum of NO has been measured in the photon energy range of 10.7-13.4eV. The spectrum exhibits many salient features due to autoionization. The vibrational distribution for NO⁺(Χ¹Σ⁺) is simulated by means of Franck-Condon analysis, using a harmonic or anharmonic potential energy curve for the autoionizing state. The vibrational levels of this state are substantially perturbed by the Rydberg states converging to NO⁺ (Χ¹Σ⁺).

Original language	English
Pages (from-to)	395-400
Number of pages	6
Journal	Journal of Electron Spectroscopy and Related Phenomena
Volume	79
DOIs	https://doi.org/10.1016/0368-2048(96)02880-0
State	Published - 1996/05

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Radiation
Atomic and Molecular Physics, and Optics
Condensed Matter Physics
Spectroscopy
Physical and Theoretical Chemistry

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title = "Autoionization of NO in an excited valence state affected by perturbations from valence-Rydberg mixing",

abstract = "A two-dimensional photoelectron spectrum of NO has been measured in the photon energy range of 10.7-13.4eV. The spectrum exhibits many salient features due to autoionization. The vibrational distribution for NO+(Χ1Σ+) is simulated by means of Franck-Condon analysis, using a harmonic or anharmonic potential energy curve for the autoionizing state. The vibrational levels of this state are substantially perturbed by the Rydberg states converging to NO+ (Χ1Σ+).",

author = "Koichiro Mitsuke and Yasumasa Hikosaka and Takumi Hikida and Hideo Hattori",

year = "1996",

month = may,

doi = "10.1016/0368-2048(96)02880-0",

language = "英語",

volume = "79",

pages = "395--400",

journal = "Journal of Electron Spectroscopy and Related Phenomena",

issn = "0368-2048",

publisher = "Elsevier B.V.",

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T1 - Autoionization of NO in an excited valence state affected by perturbations from valence-Rydberg mixing

AU - Mitsuke, Koichiro

AU - Hikosaka, Yasumasa

AU - Hikida, Takumi

AU - Hattori, Hideo

PY - 1996/5

Y1 - 1996/5

N2 - A two-dimensional photoelectron spectrum of NO has been measured in the photon energy range of 10.7-13.4eV. The spectrum exhibits many salient features due to autoionization. The vibrational distribution for NO+(Χ1Σ+) is simulated by means of Franck-Condon analysis, using a harmonic or anharmonic potential energy curve for the autoionizing state. The vibrational levels of this state are substantially perturbed by the Rydberg states converging to NO+ (Χ1Σ+).

AB - A two-dimensional photoelectron spectrum of NO has been measured in the photon energy range of 10.7-13.4eV. The spectrum exhibits many salient features due to autoionization. The vibrational distribution for NO+(Χ1Σ+) is simulated by means of Franck-Condon analysis, using a harmonic or anharmonic potential energy curve for the autoionizing state. The vibrational levels of this state are substantially perturbed by the Rydberg states converging to NO+ (Χ1Σ+).

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U2 - 10.1016/0368-2048(96)02880-0

DO - 10.1016/0368-2048(96)02880-0

M3 - 学術論文

AN - SCOPUS:0000902457

SN - 0368-2048

VL - 79

SP - 395

EP - 400

JO - Journal of Electron Spectroscopy and Related Phenomena

JF - Journal of Electron Spectroscopy and Related Phenomena

ER -

Autoionization of NO in an excited valence state affected by perturbations from valence-Rydberg mixing

Abstract

ASJC Scopus subject areas

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