Asymmetric dimerization of aniline-ruthenium-dioxolene complex driven by stepwise PCET

T. Kikuchi; K. Kobayashi; K. Tsuge; S. Kitagawa; K. Tanaka

doi:10.1039/c6dt02573k

Asymmetric dimerization of aniline-ruthenium-dioxolene complex driven by stepwise PCET

T. Kikuchi, K. Kobayashi, K. Tsuge, S. Kitagawa, K. Tanaka^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

The base-assisted oxidation of an aniline-Ru-quinone complex produced an anilinyl radical-Ru-semiquinone. Furthermore, base-assisted oxidation of the radical complex resulted in selective C-N bond formation through an intermolecular coupling between nitrogen and carbon atoms at the para-position of the anilinyl ligand.

Original language	English
Pages (from-to)	14030-14034
Number of pages	5
Journal	Dalton Transactions
Volume	45
Issue number	36
DOIs	https://doi.org/10.1039/c6dt02573k
State	Published - 2016

ASJC Scopus subject areas

Inorganic Chemistry

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title = "Asymmetric dimerization of aniline-ruthenium-dioxolene complex driven by stepwise PCET",

abstract = "The base-assisted oxidation of an aniline-Ru-quinone complex produced an anilinyl radical-Ru-semiquinone. Furthermore, base-assisted oxidation of the radical complex resulted in selective C-N bond formation through an intermolecular coupling between nitrogen and carbon atoms at the para-position of the anilinyl ligand.",

author = "T. Kikuchi and K. Kobayashi and K. Tsuge and S. Kitagawa and K. Tanaka",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2016.",

year = "2016",

doi = "10.1039/c6dt02573k",

language = "英語",

volume = "45",

pages = "14030--14034",

journal = "Dalton Transactions",

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publisher = "Royal Society of Chemistry",

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T1 - Asymmetric dimerization of aniline-ruthenium-dioxolene complex driven by stepwise PCET

AU - Kikuchi, T.

AU - Kobayashi, K.

AU - Tsuge, K.

AU - Kitagawa, S.

AU - Tanaka, K.

N1 - Publisher Copyright: © The Royal Society of Chemistry 2016.

PY - 2016

Y1 - 2016

N2 - The base-assisted oxidation of an aniline-Ru-quinone complex produced an anilinyl radical-Ru-semiquinone. Furthermore, base-assisted oxidation of the radical complex resulted in selective C-N bond formation through an intermolecular coupling between nitrogen and carbon atoms at the para-position of the anilinyl ligand.

AB - The base-assisted oxidation of an aniline-Ru-quinone complex produced an anilinyl radical-Ru-semiquinone. Furthermore, base-assisted oxidation of the radical complex resulted in selective C-N bond formation through an intermolecular coupling between nitrogen and carbon atoms at the para-position of the anilinyl ligand.

UR - http://www.scopus.com/inward/record.url?scp=84987814235&partnerID=8YFLogxK

U2 - 10.1039/c6dt02573k

DO - 10.1039/c6dt02573k

M3 - 学術論文

C2 - 27535700

AN - SCOPUS:84987814235

SN - 1477-9226

VL - 45

SP - 14030

EP - 14034

JO - Dalton Transactions

JF - Dalton Transactions

IS - 36

ER -

Asymmetric dimerization of aniline-ruthenium-dioxolene complex driven by stepwise PCET

Abstract

ASJC Scopus subject areas

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