Asymmetric diels-alder cycloaddition with chiral 2-alkylsulfinyl-1-nitroalkenes

Kaoru Fuji*, Kiyoshi Tanaka, Hitoshi Abe, Akichika Itoh, Manabu Node, Tooru Taga, Yoshihisa Miwa, Motoo Shiro

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

22 Scopus citations

Abstract

The Diels-Alder reaction of chiral 2-alkylsulfinyl-1-nitroalkene 1 and Danishefsky's diene (2) afforded adducts 3 and 4 in good chemical yield with a high enantiomeric excess, while diastereomeric nitroalkene 7 gave 8 and 9, enantiomeric to 3 and 4, respectively,.

Original languageEnglish
Pages (from-to)179-182
Number of pages4
JournalTetrahedron Asymmetry
Volume2
Issue number3
DOIs
StatePublished - 1991

ASJC Scopus subject areas

  • Catalysis
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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