TY - JOUR
T1 - Applicability of InertSep ME-2 to Solid-Phase Extraction of Trace Elements
AU - Kagaya, Shigehiro
AU - Aoki, Yukari
AU - Saeki, Yumi
AU - Goto, Taro
AU - Ohki, Mayu
AU - Obata, Issei
AU - Saito, Masaya
AU - Shirota, Riko
AU - Gemmei-Ide, Makoto
PY - 2017
Y1 - 2017
N2 - The potential of a chelating resin, InertSep ME-2, on which both iminodiacetic acid(IDA)and amine are immobilized independently, was investigated. The solid-phase extraction behavior for 21 elements using InertSep ME-2 was similar to those using Nobias Chelate PA-1, Presep PolyChelate, and a chelating resin immobilizing carboxymethylated polyethylenimine; Mg, Ca, and Sr were scarcely extracted under acidic and neutral conditions, and other elements, including Cd, Co, Cu, Fe, Mo, Ni, Pb, V, and Zn, were quantitatively recovered over a wide pH range. Such selectivity would be due to the presence of both the IDA group for the extraction of elements and the protonated amino group for the electrostatic repulsion. A significant change in extraction percentages was not observed at a flow rate of at least 30 mL/min. This could be partly due to the use of a highly cross-linked, macroporous, hydrophilic methacrylate resin as the base polymer. InertSep ME-2 was applicable to the separation of the elements in artificial seawater and some certified reference materials, EnviroMAT Ground Water ES-L-1 and Waste Water EU-L-3.
AB - The potential of a chelating resin, InertSep ME-2, on which both iminodiacetic acid(IDA)and amine are immobilized independently, was investigated. The solid-phase extraction behavior for 21 elements using InertSep ME-2 was similar to those using Nobias Chelate PA-1, Presep PolyChelate, and a chelating resin immobilizing carboxymethylated polyethylenimine; Mg, Ca, and Sr were scarcely extracted under acidic and neutral conditions, and other elements, including Cd, Co, Cu, Fe, Mo, Ni, Pb, V, and Zn, were quantitatively recovered over a wide pH range. Such selectivity would be due to the presence of both the IDA group for the extraction of elements and the protonated amino group for the electrostatic repulsion. A significant change in extraction percentages was not observed at a flow rate of at least 30 mL/min. This could be partly due to the use of a highly cross-linked, macroporous, hydrophilic methacrylate resin as the base polymer. InertSep ME-2 was applicable to the separation of the elements in artificial seawater and some certified reference materials, EnviroMAT Ground Water ES-L-1 and Waste Water EU-L-3.
KW - 固相抽出分離
KW - キレート樹脂
KW - InertSep ME-1
KW - InertSep ME-2
KW - 微量元素
KW - Solid-phase extraction
KW - Chelating resin
KW - Trace elements
U2 - 10.11457/swsj.71.5_282
DO - 10.11457/swsj.71.5_282
M3 - 学術論文
SN - 0369-4550
VL - 71
SP - 282
EP - 290
JO - Bulletin of the Society of Sea Water Science, Japan
JF - Bulletin of the Society of Sea Water Science, Japan
IS - 5
ER -