Accessible protocol for asymmetric hydroformylation of vinylarenes using formaldehyde

Tsumoru Morimoto; Tetsuji Fujii; Kota Miyoshi; Gouki Makado; Hiroki Tanimoto; Yasuhiro Nishiyama; Kiyomi Kakiuchi

doi:10.1039/c5ob00378d

Accessible protocol for asymmetric hydroformylation of vinylarenes using formaldehyde

Tsumoru Morimoto^*, Tetsuji Fujii, Kota Miyoshi, Gouki Makado, Hiroki Tanimoto, Yasuhiro Nishiyama, Kiyomi Kakiuchi

^*Corresponding author for this work

Biorecognition Chemistry

Research output: Contribution to journal › Article › peer-review

36 Scopus citations

Abstract

We report herein on an accessible protocol for the asymmetric hydroformylation of vinylarenes using formaldehyde as a substitute for syngas. The regioselectivity (branched/linear = up to 96/4) and enantioselectivity (up to 95% ee) can be attributed to the use of chiral Ph-bpe as a ligand.

Original language	English
Pages (from-to)	4632-4636
Number of pages	5
Journal	Organic and Biomolecular Chemistry
Volume	13
Issue number	16
DOIs	https://doi.org/10.1039/c5ob00378d
State	Published - 2015/04/28

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1039/c5ob00378d

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title = "Accessible protocol for asymmetric hydroformylation of vinylarenes using formaldehyde",

abstract = "We report herein on an accessible protocol for the asymmetric hydroformylation of vinylarenes using formaldehyde as a substitute for syngas. The regioselectivity (branched/linear = up to 96/4) and enantioselectivity (up to 95% ee) can be attributed to the use of chiral Ph-bpe as a ligand.",

author = "Tsumoru Morimoto and Tetsuji Fujii and Kota Miyoshi and Gouki Makado and Hiroki Tanimoto and Yasuhiro Nishiyama and Kiyomi Kakiuchi",

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AU - Morimoto, Tsumoru

AU - Fujii, Tetsuji

AU - Miyoshi, Kota

AU - Makado, Gouki

AU - Tanimoto, Hiroki

AU - Nishiyama, Yasuhiro

AU - Kakiuchi, Kiyomi

PY - 2015/4/28

Y1 - 2015/4/28

N2 - We report herein on an accessible protocol for the asymmetric hydroformylation of vinylarenes using formaldehyde as a substitute for syngas. The regioselectivity (branched/linear = up to 96/4) and enantioselectivity (up to 95% ee) can be attributed to the use of chiral Ph-bpe as a ligand.

AB - We report herein on an accessible protocol for the asymmetric hydroformylation of vinylarenes using formaldehyde as a substitute for syngas. The regioselectivity (branched/linear = up to 96/4) and enantioselectivity (up to 95% ee) can be attributed to the use of chiral Ph-bpe as a ligand.

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U2 - 10.1039/c5ob00378d

DO - 10.1039/c5ob00378d

M3 - 学術論文

AN - SCOPUS:84927667614

SN - 1477-0520

VL - 13

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EP - 4636

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

IS - 16

ER -

Accessible protocol for asymmetric hydroformylation of vinylarenes using formaldehyde

Abstract

ASJC Scopus subject areas

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