TY - JOUR
T1 - Accelerated methanol synthesis in catalytically active supercritical fluid
AU - Reubroycharoen, P.
AU - Vitidsant, T.
AU - Asami, K.
AU - Yoneyama, Y.
AU - Tsubaki, N.
N1 - Funding Information:
Financial support from New Energy and Industrial Technology Development Organization (NEDO) of Japan is greatly appreciated.
PY - 2003/9
Y1 - 2003/9
N2 - The conversion of methanol synthesis was significantly increased when supercritical 2-butanol was used. According to the property of a supercritical fluid, which facilitates heat and product removal, supercritical 2-butanol conventionally promoted the conversion of the methanol synthesis from syngas. Furthermore, supercritical 2-butanol, used as a solvent, had a catalytic effect accelerating a new reaction route. The combination of supercritical fluid and catalytic solvent effects broke through the thermodynamic limitation of the reaction efficiency.
AB - The conversion of methanol synthesis was significantly increased when supercritical 2-butanol was used. According to the property of a supercritical fluid, which facilitates heat and product removal, supercritical 2-butanol conventionally promoted the conversion of the methanol synthesis from syngas. Furthermore, supercritical 2-butanol, used as a solvent, had a catalytic effect accelerating a new reaction route. The combination of supercritical fluid and catalytic solvent effects broke through the thermodynamic limitation of the reaction efficiency.
UR - http://www.scopus.com/inward/record.url?scp=1642345178&partnerID=8YFLogxK
U2 - 10.1016/S1566-7367(03)00113-4
DO - 10.1016/S1566-7367(03)00113-4
M3 - 学術論文
AN - SCOPUS:1642345178
SN - 1566-7367
VL - 4
SP - 461
EP - 464
JO - Catalysis Communications
JF - Catalysis Communications
IS - 9
ER -