A short synthesis of optically active corey lactone by means of the dirhodium(II)-catalyzed intramolecular C-H insertion reaction of an α-diazo ketone

Takayuki Yakura; Seiji Yamada; Miki Azuma; Akiharu Ueki; Masazumi Ikeda

doi:10.1055/s-1998-2095

A short synthesis of optically active corey lactone by means of the dirhodium(II)-catalyzed intramolecular C-H insertion reaction of an α-diazo ketone

Takayuki Yakura^*, Seiji Yamada, Miki Azuma, Akiharu Ueki, Masazumi Ikeda

^*Corresponding author for this work

Synthetic and Biomolecular Organic Chemistry

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

Optically active Corey lactone 8 has been synthesized using a dirhodium(II)-catalyzed intramolecular C-H insertion reaction of chiral α- diazo-β-oxo ester 2 as a key step.

Original language	English
Pages (from-to)	973-974
Number of pages	2
Journal	Synthesis
Issue number	7
DOIs	https://doi.org/10.1055/s-1998-2095
State	Published - 1998/07

Keywords

2- oxocyclopentanecarboxylate
Corey lactone
Dirhodium(II) tetraacetate
Dirhodium(II)-catalyzed intramolecular C-H insertion
α-diazo ketone

ASJC Scopus subject areas

Catalysis
Organic Chemistry

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10.1055/s-1998-2095

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title = "A short synthesis of optically active corey lactone by means of the dirhodium(II)-catalyzed intramolecular C-H insertion reaction of an α-diazo ketone",

abstract = "Optically active Corey lactone 8 has been synthesized using a dirhodium(II)-catalyzed intramolecular C-H insertion reaction of chiral α- diazo-β-oxo ester 2 as a key step.",

keywords = "2- oxocyclopentanecarboxylate, Corey lactone, Dirhodium(II) tetraacetate, Dirhodium(II)-catalyzed intramolecular C-H insertion, α-diazo ketone",

author = "Takayuki Yakura and Seiji Yamada and Miki Azuma and Akiharu Ueki and Masazumi Ikeda",

year = "1998",

month = jul,

doi = "10.1055/s-1998-2095",

language = "英語",

pages = "973--974",

journal = "Synthesis",

issn = "0039-7881",

publisher = "Georg Thieme Verlag",

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T1 - A short synthesis of optically active corey lactone by means of the dirhodium(II)-catalyzed intramolecular C-H insertion reaction of an α-diazo ketone

AU - Yakura, Takayuki

AU - Yamada, Seiji

AU - Azuma, Miki

AU - Ueki, Akiharu

AU - Ikeda, Masazumi

PY - 1998/7

Y1 - 1998/7

N2 - Optically active Corey lactone 8 has been synthesized using a dirhodium(II)-catalyzed intramolecular C-H insertion reaction of chiral α- diazo-β-oxo ester 2 as a key step.

AB - Optically active Corey lactone 8 has been synthesized using a dirhodium(II)-catalyzed intramolecular C-H insertion reaction of chiral α- diazo-β-oxo ester 2 as a key step.

KW - 2- oxocyclopentanecarboxylate

KW - Corey lactone

KW - Dirhodium(II) tetraacetate

KW - Dirhodium(II)-catalyzed intramolecular C-H insertion

KW - α-diazo ketone

UR - http://www.scopus.com/inward/record.url?scp=0031825110&partnerID=8YFLogxK

U2 - 10.1055/s-1998-2095

DO - 10.1055/s-1998-2095

M3 - 学術論文

AN - SCOPUS:0031825110

SN - 0039-7881

SP - 973

EP - 974

JO - Synthesis

JF - Synthesis

IS - 7

ER -

A short synthesis of optically active corey lactone by means of the dirhodium(II)-catalyzed intramolecular C-H insertion reaction of an α-diazo ketone

Abstract

Keywords

ASJC Scopus subject areas

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