A mild dehydrazination reaction of arylhydrazines using nitric oxide in the presence of oxygen

Yûji Matsuya; Takashi Itoh; Kazuhiro Nagata; Akio Ohsawa

doi:10.1016/S0040-4020(97)10056-4

A mild dehydrazination reaction of arylhydrazines using nitric oxide in the presence of oxygen

Yûji Matsuya, Takashi Itoh, Kazuhiro Nagata, Akio Ohsawa^*

^*Corresponding author for this work

Synthetic and Medicinal Chemistry

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

A new dehydrazination reaction of arylhydrazines using nitric oxide and oxygen as a mild nitrosating agent is described. Taking advantage of non-aqueous and non-acidic medium appears to cause this novel selectivity as a counterpart of the azide synthesis by the conventional methods. The generally and reaction mechanism were also investigated.

Original language	English
Pages (from-to)	15701-15710
Number of pages	10
Journal	Tetrahedron
Volume	53
Issue number	46
DOIs	https://doi.org/10.1016/S0040-4020(97)10056-4
State	Published - 1997/11/17

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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title = "A mild dehydrazination reaction of arylhydrazines using nitric oxide in the presence of oxygen",

abstract = "A new dehydrazination reaction of arylhydrazines using nitric oxide and oxygen as a mild nitrosating agent is described. Taking advantage of non-aqueous and non-acidic medium appears to cause this novel selectivity as a counterpart of the azide synthesis by the conventional methods. The generally and reaction mechanism were also investigated.",

author = "Y{\^u}ji Matsuya and Takashi Itoh and Kazuhiro Nagata and Akio Ohsawa",

note = "Funding Information: This work was supported in part by a Grant-in-Aid for Scientific Research from the Ministry of Education, Science, Sports, and Culture of Japan.",

year = "1997",

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T1 - A mild dehydrazination reaction of arylhydrazines using nitric oxide in the presence of oxygen

AU - Matsuya, Yûji

AU - Itoh, Takashi

AU - Nagata, Kazuhiro

AU - Ohsawa, Akio

N1 - Funding Information: This work was supported in part by a Grant-in-Aid for Scientific Research from the Ministry of Education, Science, Sports, and Culture of Japan.

PY - 1997/11/17

Y1 - 1997/11/17

N2 - A new dehydrazination reaction of arylhydrazines using nitric oxide and oxygen as a mild nitrosating agent is described. Taking advantage of non-aqueous and non-acidic medium appears to cause this novel selectivity as a counterpart of the azide synthesis by the conventional methods. The generally and reaction mechanism were also investigated.

AB - A new dehydrazination reaction of arylhydrazines using nitric oxide and oxygen as a mild nitrosating agent is described. Taking advantage of non-aqueous and non-acidic medium appears to cause this novel selectivity as a counterpart of the azide synthesis by the conventional methods. The generally and reaction mechanism were also investigated.

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U2 - 10.1016/S0040-4020(97)10056-4

DO - 10.1016/S0040-4020(97)10056-4

M3 - 学術論文

AN - SCOPUS:0030836145

SN - 0040-4020

VL - 53

SP - 15701

EP - 15710

JO - Tetrahedron

JF - Tetrahedron

IS - 46

ER -

A mild dehydrazination reaction of arylhydrazines using nitric oxide in the presence of oxygen

Abstract

ASJC Scopus subject areas

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