急冷凝固法により作製したマグネシウム蓄電池用Mg-Al-Ca 系負極材料薄帯の電気化学活性に及ぼす Sn 添加の影響

Translated title of the contribution: Effect of Sn addition on electrochemical activity of ribbons of Mg-Al-Ca anode material for rechargeable magnesium batteries fabricated by rapid solidification

Yoshitaka Fukuta, Kensei Kikura, Tadayoshi Tsukeda*, Tetsuo Aida, Hironobu Tabata, Hideki Kurihara, Mayumi Suzuki

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

Magnesium-based batteries are potential candidates for next-generation rechargeable batteries due to the divalent nature of magnesium cations and the natural abundance of magnesium resources. In this study, the electrochemical activity of Mg-6mass%Al-3mass%Ca anodes combined with Sn was investigated. Thin ribbons of the anode specimens were prepared by a single-roll rapid solidification method. The results showed that the electrochemical activity increased upon adding 1 mass% Sn, while it decreased for 3 mass% Sn. Based on the results of an X-ray diffraction analysis, the addition of Sn led to the formation of Mg2Sn and Ca2Sn phases, which increased the lattice distortion. Scanning electron microscopy observations indicated that these secondary phases were homogeneously distributed for 1 mass% Sn addition, while they were coarsely distributed for 3 mass% Sn.

Translated title of the contributionEffect of Sn addition on electrochemical activity of ribbons of Mg-Al-Ca anode material for rechargeable magnesium batteries fabricated by rapid solidification
Original languageJapanese
Pages (from-to)9-13
Number of pages5
JournalKeikinzoku/Journal of Japan Institute of Light Metals
Volume75
Issue number1
DOIs
StatePublished - 2025

ASJC Scopus subject areas

  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

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