Steroselective Intramolecular Cyclization Using Palladium Catalyst and Its Application to the Synthesis of Natsural Products

  • 平井, 美朗 (Principal Investigator)

Project Details

Abstract

The cyclo-adducts obtained were proved to be useful chiral building blocks by their conversion into (+)-prosopinine, (-)-SS20846A, (+)-Deoxymannojirimycin, and (-)-hydroxysedamine, respectively
StatusFinished
Effective start/end date1998/01/01 → 1999/12/31

Funding

  • Japan Society for the Promotion of Science: ¥3,300,000.00

Keywords

  • 2価のパラジウム触媒
  • 高立体選択的
  • 分子内環化反応
  • Prosopinine
  • SS 20 846A
  • hydroxy sedamine
  • prosopinine
  • SS20846A
  • パラジウム錯体
  • 消化管運動抑制作用
  • (S)-glycidol
  • 1-deoxymannojirimycin
  • グリコシダーゼ阻害作用
  • アザ糖類
  • stereoselective cyclization
  • palladium (II) catalyst
  • silver trifluoroacetate
  • trans(2,6)piperidine
  • trans(2,4)piperidine
  • (+)-prosopinine
  • (-)-SS20846A
  • (+)-Deoxymannojirimycin

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