Research output per year
Research output per year
Project Details
Outline of Final Research Achievements
Asymmetric synthesis of (－)-E-δ-viniferin, a trans-resveratrol dimer natural product containing a dihydrobenzofuran ring, has been achieved by exploiting Rh(II)-catalyzed intramolecular C-H insertion reaction of a diaryldiazomethane derivative as a key step.
| Status | Finished |
|---|---|
| Effective start/end date | 2012/04/01 → 2015/03/31 |
Funding
- Japan Society for the Promotion of Science: ¥5,330,000.00
Keywords
- 複素環化合物
- C-H結合活性化
- 生物活性天然物
- C-H挿入反応
- 触媒反応
- ロジウム(II)錯体
- 不斉合成
- ジヒドロベンゾフラン
- C-Hオレフィン化
- ロジウム(II)触媒
- ネオリグナン
- スチルベンダイマー
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Diastereo- and enantioselective intramolecular 1,6-C-H insertion reactions of α-diazo esters catalyzed by chiral dirhodium(II) carboxylates
Ito, M., Kondo, Y., Nambu, H., Anada, M., Takeda, K. & Hashimoto, S., 2015/03/11, In: Tetrahedron Letters. 56, 11, p. 1397-1400 4 p.Research output: Contribution to journal › Article › peer-review
32 Scopus citations -
A 2-iodobenzamide catalyst for oxidation of alcohols at room temperature
Yakura, T., Yamada, A., Noda, N., Fujiwara, T. & Nambu, H., 2014/04, In: Asian Journal of Organic Chemistry. 3, 4, p. 421-424 4 p.Research output: Contribution to journal › Article › peer-review
11 Scopus citations -
Asymmetric Total Synthesis of (-)- trans -Blechnic Acid via Rhodium(II)-Catalyzed C-H Insertion and Palladium(II)-Catalyzed C-H Olefination Reactions
Ito, M., Namie, R., Krishnamurthi, J., Miyamae, H., Takeda, K., Nambu, H. & Hashimoto, S., 2014/01, In: Synlett. 25, 2, p. 288-292 5 p., ST-2013-U0890-L.Research output: Contribution to journal › Article › peer-review
28 Scopus citations