Project Details
Abstract
Furthermore, the absolute structure of these tree compounds were determined by the X-ray crystalogrphy. It showed that the angles between anthracene moiety and periphry in (1a) is 83° and 90°, benzene and periphery in (1b) is 37.6°, and naphthalene and periphery in (1c) is 90°, respectively. The formation of dicationic species (5a〜c) were observed in strong acid media, and dianionic species (6a〜c) also observed by the cyclic voltammogram measurement.
| Status | Finished |
|---|---|
| Effective start/end date | 1998/01/01 → 2000/12/31 |
Funding
- Japan Society for the Promotion of Science: ¥3,300,000.00
Keywords
- 直交型芳香族化合物
- アルドール反応
- 伸長反応
- 1,4-ジアセチルアントラセン
- 9、10-ジアセチルベンゼン
- 1,5-ジアセチルナフタレン
- X線構造解析
- エグリントンのカップリング反応
- 9,10-ジアセチルベンゼン
- 1、4ージアセチルアントラセン
- 9、10ージアセチルベンゼン
- 1、4-ジアセチルアントラセン
- 9、10-ジホルミルアントラセン
- Orthogonal π Conjugated Compounds
- aldol reactions
- elongation of pi conjugation
- 9,10-diacetylanthracene
- 1,4-diacetylbenzene
- 1,5-diacetylnaphthalene
- -ray crystalogrphy
- Eglinton method