Research output per year
Research output per year
Project Details
Abstract
Two classes of ethynylpyridine polymers could be prepared, one is polymer with azacrown side chains and the other is polymer with acyclic azaether side chains. Azacrown-introduced polymers showed helix stabilization and positive allosterism for saccharide recognition by the addition of oligoammonium additives as axles of rotaxane. Azaether-introduced polymers also showed helix stabilization by the addition of Cu(II) cations which coordinate with the chelating side chains.
| Status | Finished |
|---|---|
| Effective start/end date | 2009/01/01 → 2010/12/31 |
Funding
- Japan Society for the Promotion of Science: ¥4,420,000.00
Keywords
- らせん
- 円二色性
- 糖認識
- ロタキサン
- 協同効果
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Copper(ii)-mediated chiral helicity amplification and inversion of meta-ethynylpyridine polymers with metal coordination sites
Takashima, S., Abe, H. & Inouye, M., 2011/07/14, In: Chemical Communications. 47, 26, p. 7455-7457 3 p.Research output: Contribution to journal › Article › peer-review
33 Scopus citations -
Hexamethyldisilazane-Promoted Sonogashira Reaction of Polyfunctionalized N-Containing Heterocycles
井上将彦, 土井康広, 足土順一, 白土渉, 千葉順哉 & 阿部肇, 2011, In: Heterocycles. 82, p. 1137-1141Research output: Contribution to journal › Article › peer-review
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Hexamethyldisilazane-Promoted Sonogashira Reaction of Polyfunctionalized N-Containing Heterocycles
Inouye, Doi, M. ;., Azuchi, Y. ;., Shirato, J. ;., Chiba, W. ;., Abe, J. ;. & H., 2011, In: Heterocycles 82. p. 1137-1141Research output: Contribution to journal › Article › peer-review