Steroselective Construction of Nitrogen Hetero-alicycles Using Palladium Catalyst and Its Application to the Synthesis of Natsural Products

  • 平井, 美朗 (Principal Investigator)

Project Details

Abstract

The cyclo-adducts obtained were proved to be useful chiral building blocks by their conversion into (+) -prosopinine, (+) -pseudoconhydrine, and the important synthetic intermediate of (+) -palustrine, respectively
StatusFinished
Effective start/end date1994/01/01 → 1995/12/31

Funding

  • Japan Society for the Promotion of Science: ¥2,100,000.00

Keywords

  • 遷移金属錯体
  • パラジウム触媒
  • 銀塩
  • 2,6-trans-ピペリジン
  • 2,6-シス-ピペリジン
  • (+)-prosopinine
  • (+)-palastrine
  • 分子内付加環化反応
  • 2,6-cis-ピペリジン
  • (+)-palustrine
  • 分子内付加環化
  • 有機銀塩
  • 香月-Sharpless不斉酸化
  • 2,6位トランスピペジリン
  • 2,6位シスピペリジン
  • (+)-pseudoconhydrine
  • stereoselective cyclization
  • trans (2,6) piperidine
  • cis (2,6) piperidine
  • palladium (II) catalyst
  • silver trifluoroacetate
  • (+) -prosopinine
  • (+) -pseudoconhydrine
  • (+) -palustrine

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