Project Details
Abstract
The another route to the catenacene is also examined. That is, the nitration of 1,10-trimethylene-2,9-phenanthrolinedione gave 5,6-dinitro compound, and then it reduced by Sn-HClaq to give 5,6-diamino compound in good yield from starting compound. The condensation of it and the phenanthrolin-5,6-dione under the basic conditions gave phenazine derivative. Treatment of it with POCl_3 gave tetrachloro derivative in good yield as potential intermediate of catenacene. Furthemore, the use of the instrument of the middle pressure chromatogrphy made a facility of isolation of reaction products, and then it gave me a fruiteful results related researches of pi-conjugated compounds. The results of the benefits of the instrument has been appeared in the literatures.
| Status | Finished |
|---|---|
| Effective start/end date | 1996/01/01 → 1997/12/31 |
Funding
- Japan Society for the Promotion of Science: ¥2,300,000.00
Keywords
- カテナセン(仮称)
- 1、10-フェナントロリン
- 1、10-トリメチレンフェナントロリン-2、9-ジオン
- 2、9-ジホルミルフェナントロリン
- 中圧型のクロマト装置
- テトラクロロフェナントロリン誘導体
- カテナセン
- フェナントロリン
- グリニヤール試薬
- 2、9-ビス(0-トリオイル)-1、10-フェナントロリン
- 2、9-ジホルミル-1、10-フェントロリン
- 液体クロマト装置
- Catenacene
- Phenanthroline
- 2,9-diformylphenanthroline
- 1,10-torimethylenephenanthroline-2,9-dione
- tetrachlorophenanthroline derivative
- middle pressure chromatography