Keyphrases
Dirhodium Complex
100%
Spirocyclopropane
87%
Stereoselectivity
85%
Oxone
77%
Hypervalent Iodine Oxidation
76%
Ring-opening Cyclizations
69%
Diazo
62%
Methyl
58%
Stereoselective Synthesis
54%
Oxonium Ylide
52%
Tert
50%
Total Synthesis
48%
Lactones
46%
Excellent Yields
45%
C-H Insertion Reaction
45%
Room Temperature
43%
2-Iodobenzamides
43%
Tetrahydrofuran
40%
1,3-Cyclohexanedione
37%
Quinones
37%
Co-oxidant
36%
Optically Active
35%
C-H Amination
35%
Amines
33%
Rhodium(II)
32%
Phenol Derivatives
31%
Oxidative Cleavage
31%
Methanol
31%
Alkyl
31%
Hypervalent Iodine Reagents
29%
Rh(II)-catalyzed
27%
Trifluoroacetate
27%
Alcohol Oxidation
25%
2,3-Sigmatropic Rearrangement
25%
Diazoketones
24%
Phenol Oxidation
24%
Discorhabdin
23%
Intramolecular C-H Insertion
23%
Regioselective Alkylation
23%
Phenyl
22%
Indole
22%
Pachastrissamine
21%
Cephalotaxine
21%
Alkaloids
21%
Alkylation
21%
Percentage Yield
21%
Aryl
20%
Ketoesters
20%
Conjugate Addition
20%
Efficient Synthesis
20%
Chemistry
Hypervalence
98%
formation
83%
Ring Opening Reaction
72%
Insertion Reaction
60%
Lactone
55%
Stereoselective Synthesis
54%
Ambient Reaction Temperature
54%
Oxonium Ylide
53%
Quinone
42%
amination
42%
Tetrahydrofuran
42%
Rhodium
40%
Carboxylic Acid
38%
cyclohexane-1,3-dione
37%
Phenol
32%
Alkylation
32%
Oxidative Elimination Reaction
31%
Methanol
31%
Stereoselectivity
31%
Indole
30%
Chemoselectivity
29%
Ketones
27%
Dichloromethane
25%
Trifluoroacetate
24%
Sulfonium
23%
Nucleophile
21%
Furan
21%
Myriocin
21%
Cephalotaxine
21%
2,2,2-trifluoroethanol
20%
Ylide
20%
Acetonitrile
20%
Ethyl
18%
Chelation
18%
oxidation of phenols
18%
Iodoarene
18%
Ketone
18%
Natural Product
14%
Alkyl Group
14%
Cyclopentanone
14%
Catalysis
14%
3-Oxohexanoate
14%
Antitumor
14%
Sphingosine
14%
Hydrogen
14%
Baeyer-Villiger Oxidation
14%
Intramolecular Heck Reaction
14%
Addition Reaction
14%
Cycloalkane
14%
Immunomodulator
14%